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Figure 54: Gas composition entrained in the lubricant as a percentage of the gas stream at the compressor inlet.
Again, a similar trend to the coalescing filter samples is observed with the lubricant absorbing a
higher amount of the heavier hydrocarbons than methane. Figure 54 shows the percent change
relative to the inlet gas stream. It is noted that the lubricant absorbs higher proportions of the
components heavier than methane as indicated by the positive percentages. Note that the
discharge manifold samples analyzed in this section were preheated prior to depressurization
and gas analysis.
4.4.3 - Effects of Sample Heating
Between the February and June
site visits, the question was raised as to if heating the samples
prior to degassing would have any effect on the findings. To investigate this, some samples
from the June site visits were heated to 100°C (212°F) prior to depressurizing the samples. The
results of this can be seen in Figure 55.
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Figure 55: Gas composition entrained in lubricant collected at the coalescing filter for samples at room temperature
prior to degassing (left) and samples preheated to 100°C (212°F) prior to degassing (right). Note: Scale is logarithmic
to show traces of heavier hydrocarbons in gas stream.
Looking closely at Figure 55 shows that heating the samples prior to depressurizing them
releases the heavier hydrocarbons in higher concentrations than
when the samples were not
heated. The data shown in Figure 55 compares two samples collected from the discharge
coalescing filter but a similar trend was observed for samples collected from the discharge
manifold.
4.5 - Solubility - Comparison with Previous Work
The results from the field study were promising but some issues were noted. First, the lubricant
and gas had been in contact for an unknown amount of time in the field. Second, it was
unknown if past gas compositions, temperature, or pressures at the field
site could affect the
results. In contrast, the experimental apparatus described in section 3.2 - Experimental Setup
presented the opportunity to expose the lubricant to a known composition of natural gas for a
known amount of time under constant conditions. Due to these
advantages, diluted lubricant
samples were also collected from the experiment at the end of two tests conducted with natural
gas. The samples were analyzed using the methods described in section 4.3 - Sample Analysis.
The results were then compared to a calculated gas composition assuming ideal mixing based
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on the partial pressure of each gas species and the data provided by Seeton (2019). These
comparisons are shown in Figure 56 and Figure 57.
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