Membrane Gas Separation

362
Index
inorganic membranes 283–84
integrated gasifi cation combined cycle 
(IGCC) power generation 187, 187
internal sweep design 334
inverse gas chromatography 61
ion transport membranes 284
ionic liquid membranes for carbon 
dioxide separation 185–99
discussion 194–97
experimental details 189
results 189–94
ionic liquids, and carbon dioxide 
separation 188–89
iron blast furnace, minor components 202
kinetic diameter 77, 95, 98, 100, 120, 
120, 203, 203, 211, 212, 217, 291
Knudsen diffusion 88, 89–90
minimum pore size for 101
permeability for 103
Knudsen number 89
ladder polymers 30
landfi ll gas 316, 317
Langmuir affi nity constants 209, 210
Le Chatelier’s principle 187
Lennard-Jones constants 99
linear polyimides, selectivity and 
permeability 21, 22
LTA zeolite membranes 284
magnetic membranes 160
mass transport coeffi cients 171
mass transport, in dense polymer 
membranes 64
Matrimid 207, 320
chemical structure 321
Matrimid 5218 17
CO
2
permeability 216, 220, 221
gas permeability coeffi cients and 
selectivity 15, 20
H
2
S competitive sorption into 
polysulfone and 213–16
water competitive sorption into 
polysulfone and 220–22
Matrimide-H40 17
Maxwell equation 241
Maxwell model 126, 242
membrane engineering 281–312
membrane gas separation, progress and 
potentialities 281–312
membrane modules 284–85
membranes
applications in gas separation 286–300
for CO
2
removal 228
comparison of project parameters 304
current applications in gas separation 
287, 288–89
feed and product conditions 305
porous structures 90
selectivity 126
strategies for reduced size of large-
scale 327–29
mercury, critical temperature 203
metal membranes 283
methane 186
kinetic diameter and critical 
temperature 203
methanol
solubility coeffi cients 80
van der Waals volume and diffusion 
coeffi cient of clusters of 79, 79–80
vapour permeation 80
vapour transport 77
N-methyl pyrrolidone (NMP) 259
methylalumoxane (MAO) 45
methyldiethanolamine 318
methyltrimethoxysilane see MTMS 
(methyltrimethoxysilane)
MFI_80 116, 117, 117
MFI_350 116, 117, 117
MFI_1500 117, 117, 117
MFI_dC5 117, 117, 117
microporous glass 91
microporous material 29
microporous membranes, model of fl ux 
components through 97–98, 98
microporous silica, diffusive jump in 93
mixed-matrix glassy membranes
modelling gas diffusivity and 
permeability in 130–32, 132
modelling gas solubility into 128–30

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Index
363
mixed-matrix membranes (MMMs) 113, 
114, 125, 144, 159, 283
modelling
of gas molecules through pores 106
gas separation in porous membranes 
85–109
modules
performance with ideal sweep 
distribution 341–44
properties and operating conditions 
341
variety of designs 328, 329
molar absorption coeffi cients 68
molecular dynamics simulations 
71–72
molecular masses, of gases and pore 
atoms 99
molecular size, gas separation and 
differences in 159
monoethanolamine 318
monomers, self-polycondensation reaction 
of AB
2
-type 4
MTMS (methyltrimethoxysilane) 145,