The definition of technological scheme.
This is a
closed system, close to ideal, i.e. here is only the entry
of raw materials and the output of the finished product,
the losses are minimized. In order to utilize the heat of
the flue gases emitted into the atmosphere at a tempera-
ture of 370
o
C, heat recovery utilizer and recuperator are
used to obtain live steam and hot air for technological
use, thereby lowering the temperature of the flue gases
to 105-115
o
C. The developed live steam moves through
the serpentine tubes inserted into the 19/19
1
- adsorbers,
heats the membrane to 70
o
C, which breaks the chemical
bond formed by the CO
2
and the membrane, and allows
pure CO
2
to be obtained. A temperature swing desorbing
mode under vacuum was selected for the desorption pro-
cess. The heat of this live steam being produced meets
the need for heat in the installation. The flue gases enter
the 10 - mixer with ozone. Oxidized gases are acidic
gases that are easily absorbed by the absorbent. The fully
oxidized flue gases then transfer their heat to the water
of 11 - economizer (or process deaerator water) for heat-
ing. Acidic oxides are absorbed into the condensate
along with ammonia, leaving the devices in a neutral en-
vironment that does not degrade, and sent to the stable
fertilizer production unit. Uncondensed flue gases enter
the 12 - scrubber at a temperature of 40-70
o
C, where
they are also washed with ammonia water (pH = 5-10).
Stable fertilizers NH
4
NO
3
and (NH
4
)
2
SO
4
are obtained
from the formed unstable NH
4
NO
2
and (NH
4
)
2
SO
3
salts.
The non-condensed gases are sucked out of the separator
through the 13 - drip eliminator by means of a 5
1
- smoke
exhauster and fed to the 14 - compressor, from there to
the 15 - absorber, or without entering it to the 19/19
1
-
adsorber. In the 15 - absorber, SO
2
in the flue gases is
absorbed using a 30% limestone solution. As a result,
the production of gypsum - CaSO
4
from limestone
CaCO
3
is launched. Smoke gases containing mainly ni-
trogen - N
2
, O
2
, CO
2
, H
2
O and small amounts (<2 ppm)
of other acidic oxides pass through the PAM layer of the
19/19
1
-adsorber, where the CO
2
in the flue gas is
trapped. The 19/19
1
- adsorber contains PAM and oper-
ates periodically alternating with the 19
1
/19 - desorber.
For desorption, the internal pressure of the desorber is
reduced to ≤100 mbar
abs
by means of 8
2
-vacuum pump,
and using live steam the pipes inserted into the de-
sorber’s jacket and the membrane are heated gradually
to 70
o
C. The desorbed CO
2
cooled using an 16
1
- aque-
ous cooler, and sent to 20 - compression section, then to
the intended use, e.g., dry ice, acrylic acid production
unit and other petrochemical production units. In the
above-mentioned furnace, if only desulfurized techno-
logical gases are used, SO
n
, N
x
O
y
gases and aerosols are
almost absent in flue gases, in this case the scrubber is
not supplied with ammonia water, flue gases enter to the
19/19
1
- adsorber bypassing 15 – absorber.
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