Organic Chemistry I



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d
orbital is available in the
valence shell. That is why they can accommodate more than 8 electrons.
Key Takeaways
For elements in 2
nd
period, C, N, O, F and Ne, the
maximum
number of electrons involved in Lewis
structure is
eight!!!
1.2 Lewis Structure | 17


1.3 Resonance Structures
In the case that more than one reasonable (plausible) Lewis structure can be drawn for a species, these structures are
called
resonance structures
or
resonance contributors
. Resonance structures can be either equivalent or non-
equivalent.
Equivalent Resonance Structures
Let’s consider the example of carbonate anion, CO
3
2-
:
Figure 1.3a Versions of the carbonate anion Lewis structure
By following Step 6 in the
Lewis structure drawing procedure
, the double bond can be built between the central C and
any of the terminal O’s to generate three structures, and they all look “the same”. However, they are not really identical
(or same), they are just equivalent. Each structure is called a
resonance structure,
and they can be connected by the
double-headed resonance arrow. There are total three
equivalent resonance structures
for CO
3
2-
, and the actual
structure of CO
3
2-
is the
hybrid
of the three resonance contributors.
Figure 1.3b Three equivalent resonance contributors of carbonate anion
18 | 1.3 Resonance Structures


The arrows used here to connect between resonance structures is the “
resonance arrow
“, which has
double arrow heads. Resonance structures have to be connected using resonance arrows.
Since the resonance structures are equivalent, they are all in the same level of energy and have the same stability, so
they make the same contributions to the actual structure of CO
3
2-
. This is supported by the experimental evidence
that all the carbon-oxygen bonds in CO
3
2-
are the same bond length, which is longer than a regular double bond but
shorter than a single bond. As a result of the resonance structures, the two negative charges in CO
3
2-
are not localized
on any oxygen atoms, but are spread evenly among all three oxygen atoms, and is called charge
delocalization.
Because
of charge delocalization, each oxygen atom has two-thirds of a full negative charge. Charge delocalization helps to
stabilize
the whole species. The stability a species gains from having charge delocalization through resonance
contributors is called

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