Organic Chemistry I



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Organic <a href="/toshkent-kimyo-texnalogiyalar-instituti.html">Chemistry I</a>

Organic Chemistry I



Organic Chemistry I
XIN LIU
KWANTLEN POLYTECHNIC UNIVERSITY
SURREY, BC


Organic Chemistry I by Xin Liu is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License, except where
otherwise noted.


Contents
Introduction
1
Acknowledgements
4
Chapter 1 Basic Concepts in Chemical Bonding and Organic Molecules
1.1 Chemical Bonding
7
1.2 Lewis Structure
10
1.3 Resonance Structures
18
1.4 Resonance structures in Organic Chemistry
22
1.5 Valence-Shell Electron-Pair Repulsion Theory (VSEPR)
26
1.6 Valence Bond Theory and Hybridization
30
Answers to Practice Questions Chapter 1
40
Chapter 2 Fundamental of Organic Structures
2.1 Structures of Alkenes
45
2.2 Nomenclature of Alkanes
51
2.3 Functional Groups
57
2.4 IUPAC Naming of Organic Compounds with Functional Groups
64
2.5 Degree of Unsaturation/Index of Hydrogen Deficiency
70
2.6 Intermolecular Force and Physical Properties of Organic Compounds
74
Answers to Practice Questions Chapter 2
82
Chapter 3 Acids and Bases: Organic Reaction Mechanism Introduction
3.1 Review of Acids and Bases and Ka
85
3.2 Organic Acids and Bases and Organic Reaction Mechanism
87
3.3 pKa of Organic Acids and Application of pKa to Predict Acid-Base Reaction Outcome
92
3.4 Structural Effects on Acidity and Basicity
98
3.5 Lewis Acids and Lewis Bases
106
Answers to Practice Questions Chapter 3
108
Chapter 4 Conformations of Alkanes and Cycloalkanes
4.1 Conformation Analysis of Alkanes
113
4.2 Cycloalkanes and Their Relative Stabilities
121


4.3 Conformation Analysis of Cyclohexane
125
4.4 Substituted Cyclohexanes
131
Answers to Practice Questions Chapter 4
136
Chapter 5 Stereochemistry
5.1 Summary of Isomers
141
5.2 Geometric Isomers and E/Z Naming System
142
5.3 Chirality and R/S Naming System
148
5.4 Optical Activity
161
5.5 Fisher Projection
170
5.6 Compounds with More Than One Chirality Centers
174
Answers to Practice Questions Chapter 5
187
Chapter 6 Structural Identification of Organic Compounds: IR and NMR Spectroscopy
6.1 Electromagnetic Radiation and Molecular Spectroscopy
193
6.2 Infrared (IR) Spectroscopy Theory
195
6.3 IR Spectrum and Characteristic Absorption Bands
197
6.4 IR Spectrum Interpretation Practice
201
6.5 NMR Theory and Experiment
204
6.6 ¹H NMR Spectra and Interpretation (Part I)
210
6.7 ¹H NMR Spectra and Interpretation (Part II)
220
6.8 ¹³C NMR Spectroscopy
228
6.9 Structure Determination Practice
232
Answers to Practice Questions Chapter 6
237
Chapter 7 Nucleophilic Substitution Reactions
7.1 Nucleophilic Substitution Reaction Overview
241
7.2 SN2 Reaction Mechanism, Energy Diagram and Stereochemistry
245
7.3 Other Factors that Affect SN2 Reactions
250
7.4 SN1 Reaction Mechanism, Energy Diagram and Stereochemistry
254
7.5 SN1 vs SN2
261
7.6 Extra Topics on Nucleophilic Substitution Reaction
267
Answers to Practice Questions Chapter 7
274
Chapter 8 Elimination Reactions
8.1 E2 Reaction
279
8.2 E1 Reaction
285
8.3 E1/E2 Summary
288


8.4 Comparison and Competition Between SN1, SN2, E1 and E2
289
Answers to Practice Questions Chapter 8
294
Chapter 9 Free Radical Substitution Reaction of Alkanes
9.1 Homolytic and Heterolytic Cleavage
297
9.2 Halogenation Reaction of Alkanes
299
9.3 Stability of Alkyl Radicals
305
9.4 Chlorination vs Bromination
307
9.5 Stereochemistry for Halogenation of Alkanes
312
9.6 Synthesis of Target Molecules: Introduction of Retrosynthetic Analysis
314
Answers to Practice Questions Chapter 9
317
Chapter 10 Alkenes and Alkynes
10.1 Synthesis of Alkenes
321
10.2 Reactions of Alkenes: Addition of Hydrogen Halide to Alkenes
326
10.3 Reactions of Alkenes: Addition of Water (or Alcohol) to Alkenes
332
10.4 Reactions of Alkenes: Addition of Bromine and Chlorine to Alkenes
337
10.5 Reaction of Alkenes: Hydrogenation
344
10.6 Two Other Hydration Reactions of Alkenes
346
10.7 Oxidation Reactions of Alkenes
351
10.8 Alkynes
358
Answers to Practice Questions Chapter 10
367
About the Author
371



Introduction

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