(2005-DTM.)
1. [Pt(NH3)6]Cl4 kompleks birikmadagi markaziy atomning gibridlanish turini aniqlang.
A) sp3 B) sp3d1 C) sp D) sp3d2 E) sp2
2. Qattiq uglerod(IV) oksid (quruq muz)ning
tuzilishi qanday xususiyatlar bilan ifodalanadi?
A) sp3-gibridlanish, burchak 1090, molekulyar kristall panjarali
B) sp2-gibridlanish, burchak 1200, atom kristall panjarali
C) sp-gibridlanish, burchak 1800, molekulyar kristall panjarali
D) sp-gibridlanish, burchak 1800, atom kristall panjarali
E) sp2-gibridlanish, burchak 1200, molekulyar kristall panjarali
3. Bor ftorid molekulasidagi B atomi valent orbitalining gibridlanishi va molekuladagi atomlar orasidagi burchakni toping.
A) sp3, 1090,28’ B) sp2, 1800 C) sp, 1800
D) sp, 1200 E) sp2, 1200
4. Kumol molekulasidagi benzol halqasi bilan bevosita bog‘langan uglerod atomining oksidlanish darajasi ... ga teng bo‘lib, u ... gibridlangan holatidadir.
A) -1; sp3 B) -2; sp3 C) +1; sp2 D) +3; sp2 E) 0; sp
5. Ammiak molekulasining fazoviy tuzilishi va markaziy atomining gibridlanishi-
A) piramida va sp3 B) chiziqli va sp
C) teng tomonli uchburchak va sp3
D) tetraedr va sp3 E) kvadrat va sp2
6. Chumoli kislotadagi uglerod atomining oksidlanish darajasi va gibridlanish turini toping.
A) 0, sp2 B) +1, sp2 C) +1, sp D) +2, sp2 E) +2, sp
7. Kalsiy karbid gidrolizi natijasida hosil bo‘lgan gaz mahsulot aktivlangan ko‘mir ustidan o‘tkazilganda olingan aromatik modda tarkibidagi uglerod atomlarining oksidlanish darajasi va gibridlanishi-
A) 0 va sp2 B) +1 va sp C) +1 va sp2 D) -1 va sp2
E) -1 va sp
8. Qaysi molekulaning markaziy atomi sp3 gibridlangan bo‘lib, burchakli fazoviy tuzilishga ega?
1) CO2 2) NH3 3) SO3 4) CH4 5) C2H2 6) H2O.
A) 1, 3 B) 4, 5 C) 2 D) 6 E) 3, 6
9. CH4, NH3, H2O qatoridagi molekulalarning valent burchagi qanday o‘zgaradi?
A) o‘zgarmaydi
B) oldiniga kamayadi, so‘ngra ortadi C) kamayadi
D) oldiniga ortadi, so‘ngra kamayadi E) ortadi
10. Qaysi molekulalarning markaziy atomi sp2 gibridlangan holatda bo‘ladi?
1) H2O 2) SO2 3) SO3 4) CO2 5) NH3 6) CH4
A) 2,3,5 B) 2,3 C) 1,5,6 D) 3,4,5 E) 2,4
11. Silan molekulasining geometrik shakli qanday?
A) tetraedr B) burchakli C) chiziqli D) oktaedr
E) kvadrat
12. Qaysi moddalar molekulasida markaziy atom sp3- gibridlanish holida bo‘ladi?
A) SiH4, CH4, C2H4 B) BeF2, H2O, NH3
C) CH4, H2O, NH3 D) H2O, SO2, BeF2
E) BCl3, NH3, C2H2
13. Berilliy ftorid molekulasidagi berilliy atomi valent orbitalining gibridlanishi va molekulaning tuzilishini aniqlang:
A) sp2, yassi B) sp2, chiziqli C) sp, yassi
D) sp3, tetraedr E) sp, chiziqli
14. Metan molekulasidagi uglerod atomining gibridlanishi va fazoviy tuzilishini aniqlang.
A) sp3, tetraedr B) sp2, oktaedr C) sp, chiziqli
D) sp3, yassi E) sp2, yassi
15. Quyidagi molekulalarning qaysilarida markaziy atomning gibridlanishi sp holatda bo‘ladi?
1) BeCl2 2) CO2 3) H2O 4) SO2
A) 1,2 B) 1,4 C) 3,4 D) 1,3 E) 2,3
16. Uglerod(IV) oksid molekulasida uglerod atomining gibridlanish turini va buning sababini aniqlang.
a) sp; b) sp2; c) sp3;
1) uglerod atomining barcha valent elektronlari bog‘ hosil bo‘lishda ishtirok etadi; 2) uglerod atomi 2r-orbitalda ikkita juftlashmagan elektronlarga ega; 3) SO2 molekulasi chiziqli tuzilishga ega
A) a-3 B) b-3 C) a-1 D) s-1 E) b-2
17. Quyida berilgan molekulalar markaziy atomlarining gibridlanish tiplarini aniqlang.
1) BeH2 2) BF3 3) CCI4 4) NH3 5) H2O
A) sp3, sp2, sp3, sp, sp3 B) sp, sp, sp3, sp3, sp3
C) sp, sp2, sp3, sp2, sp3 D) sp, sp2, sp3, sp3, sp3
E) sp2, sp, sp3, sp2, sp3
18. Qaysi moddalar molekulasida markaziy atom gibridlanishi sp, sp2, sp3 tartibda bo‘ladi?
A) SiH4, CH4, C2H4 B) BeF2, H2O, NH3
C) CH4, H2O, NH3 D) SO2, SO2, SiO2
E) BCl3, NH3, C2H2
19. sp2-gibridlangan orbitallar yo‘nalishlari orasidagi burchak qanday bo‘ladi?
A) 1200 B) 10405’ C) 1800 D) 109028’ E) 900
20. Qaysi molekulaning markaziy atomi sp2 gibridlangan bo‘lib, burchakli fazoviy tuzilishga ega?
1) CO2 2) NH3 3) SO3 4) CH4 5) C2H2 6) H2O.
A) 1, 3 B) 4, 5 C) 2 D) 6 E) 3
21. larning mos ravishda gibridlanish holati-
A) sp2; sp2; sp3; sp3 B) sp2; sp3; sp2; sp3d
C) sp2; sp; sp2d2; sp2 D) sp3; sp; sp3; sp
E) sp2; sp3; sp3; sp3
22. Suv molekulasidagi kimyoviy bog‘lanishda qaysi orbitallardagi elektronlar ishtirok etadi?
A) 2s-2p B) 2p-2p C) 1s-2p D) 2s-2s E) 1s-2s
23. Qaysi molekulalarning markaziy atomi sp3 gibridlangan holatda bo‘ladi?
1) H2O 2) SO2 3) SO3 4) CO2 5) NH3 6) CH4
A) 2,3,5 B) 2,3 C) 1,5,6 D) 3,4,5 E) 2,4
24. N3O+; ionlar markaziy atomining gibridlanish holatini va ularning fazoviy shaklini aniqlang.
1) sp3; 2) sp2; 3) sp; 4) piramida; 5) tetraedr
6) teng tomonli uchburchak; 7) kvadrat
A) 3,4; 3,6 B) 1,4; 1,5 C) 1,4; 1,7 D) 1,4; 2,4 E) 2,6; 2,7
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