Ii bob. Olingan natijalar tahlili

CDCl₃da Delfelinning NMR spektral ma'lumotlari.
δ_H (CDCl₃)(400 MHz), 5.13 (1H, s, O-CH 2 -O), 5.05 (1H, s, O-CH 2 -O), 4.20 (1H, s, H-6), 3.68-3.66 (1H, m, H-14), 3.64 (1H, t, J = 5 Hz, H-9), 3.42 (3H, s, C-14-OMe), 3.35 (3H, s, C-16-OMe), 3.26 (3H, s, C-1-OMe), 3.25-3.23 (1H, m, H-16), 3.09-3.02 (2H ustma-ust , m, H-1 va H-17), 2.78 (1H, br s, NCH 2 CH 3 ), 2.66 (1H, br s, NCH 2 CH 3 ), 2.66 (1H, br s, H-19), 2.55 (1H, m, H-12), 2.49 (1H, dd, J = 14.9,8.8 Hz, H-15), 2.37 (1H, br s, H-13), 2.20 (1H, d, J = 5 Hz, H-19), 2.19-2.10 (1H, m, H-10), 2.19-2.08 (1H, m, H-2), 2.04-1.96 (1H, m, H-2), 1.86-1.82 (1H, m, H-15), 1.82 (1H, m, H-12), 1.52 (1H, t, J = 7.2 Hz, H-3), 1.23 (1H, t, J = 7.2 Hz H-3), 1.24-1.22 (1H, m, H-5), 1.05 (3H, t, J = 6.9 Hz, NCH 2 CH 3 ), 0.93 (3H, s, H-18).
δ C (CDCl 3 ) (125 MHz), 93.0 (O-CH 2 -O), 92.5 (C-7), 84.0 (C-8), 83.1 (C-14), 82.8 (C-1), 81.9 (C-16), 79.3 (C-6), 63.7 (C-17), 57.3 (C-19), 58.0 (14-OMe), 56.4 (16-OMe), 56.6 (C-5), 55.7 (1-OMe), 50.8 (NCH 2 CH 3 ), 50.5 (C-11), 47.8 (C-10), 40.4 (C-9), 37.8 (C-13), 37.0 (C-3), 34.0 (C-4), 33.5 (C-15), 28.2 (C-12), 26.0 (C-2), 25.5 (C-18), 14.2 (NCH 2 CH 3 );[20].
Delfelinning MH + ning 450,2878 (∆ 1,9 ppm) molekulyar formulasi C₂₅H₄₀NO₆
CDCl₃ da Metillikakonitinning NMR spektral ma'lumotlari.
δ H (CDCl₃) (400 MHz), 8.03 (1H, d, J = 8.5 Hz, H-6'), 7.67 (1H, t, J = 8.5 Hz, H-4'), 7.55 (1H, t J = 8.5 Hz, H-5'), 7.27 (1H, d, J = 8.5 Hz, H-3'), 4.11 (1H, d, J = 11.2 Hz, H-18), 4.07-4.02 (1H, m, H-18), 3.87 (1H, s, H-6), 3.60 (1H, t, J = 4.6 Hz, H-14), 3.40 (3H, s, C-14-OMe), 3.34 (3H, s, C-6-OMe), 3.33 (3H, s, C-16-OMe),3.25 (3H, s, C-1-OMe), 3.20 (1H, m, H-16), 3.08-3.01 (3H ustma-ust, m, H-9, H-2" va H-3"), 3.00-2.95 (1H, m, H-1), 2.93 (1H, br s, H-17), 2.95-2.90 (1H, m, NCH₂CH₃), 2.88-2.78 (1H, m, NCH₂CH₃), 2.70 (1H, d, J = 11.5 Hz, H-19), 2.62-2.55 (1H, m, H-15), 2.50-2.35 (3H ustma-ust, m, H-12, H-3" va H-13), 2.45-2.40 (1H, m, H-19), 2.22-2.11 (1H, m, H-2), 2.10-1.88 (2H ustma-ust, m, H-2 va H-10), 1.89-1.78 (1H, m, H-12), 1.78-1.70 (2H overlapping, m, H-3 and H-5), 1.70-1.62 (1H, dd, J = 14.4, 6 Hz, H-15), 1.62-1.50 (1H, m, H-3), 1.42 (3H, m, H-5"), 1.07 (3H, t, J = 7.5 Hz, NCH 2 CH 3 ).
δ C (CDCl 3 ) (125 MHz), 179.8 (C-1"), 175.9 (C-4"), 164.0 (Ph-CO), 133.6 (C-4'), 132.5 (C-2'), 130.9 (C-6'), 130.0 (C-3'), 129.4 (C-5'), 127.0 (C-1'), 90.8 (C-6), 88.4 (C-7), 83.9 (C-1), 83.7 (C-14), 82.5 (C-16), 77.2 (C-8), 69.4 (C-18), 64.5 (C-17), 58.1 (6-OMe), 57.8 (C-14-OMe), 56.3 (C-16-OMe), 55.8 (C-1-OMe), 52.3 (C-19), 50.9 (NCH₂CH₃), 50.1 (C-5), 49.0 (C-11), 46.0 (C-10), 43.2 (C-9), 38.1 (C-13), 37.5 (C-4), 37.0 (C-3"), 35.2 (C-2"), 33.6 (C-15), 32.0 (C-3), 28.7 (C-12), 26.1 (C-2), 16.3 (C-5"), 14.0 (NCH₂CH₃); [20].
Metillikakonitinning MH + ning 683.3544(∆ 1,9 ppm) molekulyar formulasi C₃₇H₅₀N₂O_10.

Xulosa.
1. Ushbu magistrlik dissertatsiya ishini bajarish jarayonida atrofimizni o‘rab turgan o‘simliklar dunyosi turli shifobaxsh xususiyatlarga ega ekanligi adabiyotlardagi maʼlumotlarlar va qilingan amaliy ishlar asosida o‘rganildi.
2. Farg’ona viloyatida o’suvchi Delphinium stocksianum Boiss o‘simligini biz tomondan birinchi marotaba alkaloidlari tarkibi o’rganildi.
3. Delphinium stocksianum Boiss o‘simligining alkaloid tarkibini o‘rganish natijasida o‘simlikning tana a’zolaridagi alkaloidlar saqlash dinamikasi o’rganildi.
4. Delphinium stocksianum Boiss o’simligidan birinchi maratoba delfelin va metillikakonitin alkaloidlari biz tomondan ajratib olindi va tuzulishi tasdiqlandi.