№3/2021 year.
Technical science and innovation
62
Improving the equilibrium and kinetic characteristics of the most microporous coals leads
to an increase in the efficiency of carbon adsorbents in industrial conditions. When choosing the
type of adsorbent for industrial installations, two distinctive properties of activated carbons
should be taken into account: hydrophobicity and flammability.
A negative feature of activated carbon as an industrial adsorbent is its combustibility. In the
air, the oxidation of coals begins at a temperature above 250 ° C. However, there are known
cases of fires at carbon adsorption plants at lower temperatures. Obviously, this is due to the
formation of pyrophoric iron compounds such as FeS and Fe2S3 as a result of hydrogen sulfide
corrosion of the equipment.
Keywords:
Activated carbon, carbon-containing organic substances, pyrolysis, granule,
porous structure, adsorption, coal.
INTRODUCTION.
Activated carbon is the result of firing
various carbon-containing
organic substances (wood, nut shells, olives, other fruit crops, coal coke). The resulting
substance contains a huge number of pores and therefore has a very large specific surface area
per unit mass and,
as a result, high adsorption.In the porous structure of activated (otherwise
active) coal, any types of organic micro-impurities are absorbed due to the forces of surface
interaction (or adsorption).
It is the pores, their number and size, that affect the adsorption properties of coal. The
formation of the structure of activated carbon (pore) occurs in the technological process of its
production due to the use of certain raw materials and calculated
modes of its heat treatment
(carbonation, activation).Sorption capacity is the main factor of activated carbon efficiency.
Therefore, charcoal is additionally processed (activated) and as a result, coal changes its
structure - a large number of pores with different volumes are formed.
The resulting pores are classified into three categories: microspores (from 0.6 to 0.7
nanometers), microspores (1,5-100-200 nanometers), macrospores (>100-200 nanometers). The
first and second types of pores are considered the main components of the surface of active
coals.Activated carbon AG-3 is intended for adsorption from gaseous and liquid media,
including for the purification of drinking water.
AG-3 grade activated carbon is obtained in the form of granules from coal dust and binders
by steam treatment at a temperature of 850-950 °C.Active carbons
belong to hydrophobic
compounds and adsorb primarily hydrophobic substances, which include most organic
substances (adsorption activity increases with increasing molecular weight and temperature of
the adsorbent).
Active coals are obtained from various types of organic raw materials: wood, peat, brown or hard
coal,
animal bones, nut shells, etc.During production, the source material is subjected to heat
treatment without air access. In this case, volatile substances are
removed and a large-porous
structure is formed, partially filled with resinous substances.This structure is activated by
oxidizing with carbon (IV) oxide (or water vapor) at 850 - 900 °C (gas activation), or by treating
with mineral acids (or salts) at a temperature of 200 - 650 °C (chemical activation).
The name of the coals includes the reagent used for activation, for example, "chlorine
activation coal".