Classification of organic compounds 2 physical chemistry



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 The concept of functional groups is central in organic chemistry, both as a means to classify structures and for predicting properties. A functional group is a molecular module, and the reactivity of that functional group is assumed, within limits, to be the same in a variety of molecules. Functional groups can have decisive influence on the chemical and physical properties of organic compounds. Molecules are classified on the basis of their functional groups. Alcohols, for example, all have the subunit C-O-H. All alcohols tend to be somewhathydrophilic, usually form esters, and usually can be converted to the corresponding halides. Most functional groups feature heteroatoms(atoms other than C and H). Organic compounds are classified according to functional groups: alcohols, carboxylic acids, amines, etc.
Substances consisting entirely ofsingle-bonded carbon and hydrogen atoms and lacking functional groups are called alkanes. There are three basic types of structure that they are classified in: the linear straight-chain alkanesbranched alkanes, and also cycloalkanes. Alkanes can be subdivided into three groups. An alkane is also called saturated hydrocarbon because the compound has only single bonds between the atoms. Alkanes that have a ring or cyclic structure are called cyclic alkanes, while those that are without are called acyclic. General formula: CnH2n+2, n>2.
Alkenes area class of hydrocarbons that contain only carbon and hydrogens. They are unsaturated compounds that contain at least one carbon-to-carbondouble bond. Another term that is often used to describe alkenes is olefins.
Alkynes are organic molecules made of the functional group carbon-carbon triple bonds. They are written in the empirical formula of CnH2n-2. They are unsaturated hydrocarbons.
Benzene is one of the best-knownaromatic compounds as it is one of the simplest and most stable aromatics.
Aromatic hydrocarbons contain conjugateddouble bonds. This means that every carbon atom in the ring is sp2 hybridized, allowing for added stability. The most important example is benzene, the structure of which was formulated by Kekulé who first proposed the delocalization or resonance principle for explaining its structure.

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