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Chemistry and High Technology, 25, no. 1, (March 1992): 13-15. 
5
GrigoriyNebol‘sin, StatisticheksiyObozrenieVneshneTorgovliRossii, (Petersburg:TipografiyaVneshneyTorgovli, 
1850),338 
6
Chenciner,Madder Red, 341 
7
Maria 
Rojkova, 
EkonomicheskyaPolitikaTsarskogoPravitel‘stvanaSrednemVostokevoVtoroyChetverti 
XIX 
VekaiRusskayaBurjuaziya(Petersburg: 
Academy 
of 
Science 
USSR 
Press, 
1849) 
113-114; 
Karpov, 
MarenaVozdelyvaniieya v Derbent v Primenenii k OrenburgskomuKrayu (Saint Petersburg, 1859) 32 
8
UbaydullaKarimov, Abu RaykhanBeruniy (973-1048) IzbrannyeProizvedeniya 4 (Tashkent: Fan, 1974), 689-690 
9
Anette Beveridge, Baburnama in English (Memoirs of Babur) (London, Luzac, 1922), 218 
10
NikolayMurav‘ev, Muraviev‘s Journey to Khiva through the Turcoman Country, 1819–20 (Calcutta: Foreign 
Department Press, 1871) 147 


26 
commodity to Astrakhan. The localization of the madder in Khiva as cash crop started during the 
reign of Muhammad Rahim Khan (I) who consolidated the central authority of Khan by 
subjugating surrounding territories such as theAral region. He also implemented economic 
reforms and expanded the irrigationsystem by opening new canals and reviving old ones.
11
Asa 
result, irrigated territories and the volume of arable land increased during the first two decades of 
the 19
th
century in Khiva. Madder was introduced as a new cash crop andit soon became an 
important part of the agricultural development in Khiva. 
It‘s not yet clear from the available documents how the cultivation of madder initially 
started in Khiva and which regions of Khanate were specialized in madder growing. However, it 
must have taken at least a decade period until madder cultivation to became popular in Khanate 
as cash crop. According to Nebol‘sin‘s trade statistics of the Russian Empire, the early madder 
imports from Khiva started in the 1830s and thenincreased dramatically. In the 1840s, madder 
root became one of the biggest export cash crops in Khiva, if not the biggest. The quantity of 
madder export to Russia reached to almost 12000 puds in 1845 and Khiva became the largest 
madder producer in Central Asia.
12
The Khivan madder root export contributed to 20% of madder 
root imports of the Russian Empire during the 1840s, which is a significant amount when 
compared to cotton and other raw materials.In 1848, FedorPichugin, a well-known Russian 
textile merchant in Central Asia since 1816, wrote that he and his companions increased the 
trade of madder for 20.000 puds a year within the last 7 years.
13
These facts show that, Khivan 
madder export to Russia significantly rose during 1850s andRussia became the main destination 
of Khivan madder export until the 1860s. Madder was also grown in Bukhara and the Kokand 
Khanate; however, their export quantity was very limited when compared to Khiva during this 
time. 
In late 1860s synthetic dye was invented in Europe by extracting alizarin from coal tar.
14
Since then, synthetic dyes began replacing the natural dyes as an important ingredient for the 
textile industry throughout the world. Once thisformula was created, the synthetic dyes began 
manufactured massively and the price was four times cheaper than natural dyes. However, 
synthetic dyes could not replace the natural dyes immediately and it took decades for 
transitioning from natural to chemical dyes in textile industry. Madder remained as an important 
local crop in Khiva during the last quarter of the 19
th
century as well.
15
According to the archival 
materials of Alexander Kuhn, a Russian Orientalist who had immediate access to palace 
documents after annexation of Khiva, there were at least 16 madder root selling booths in Khiva 
in 1873.
16
Despite losing its export capacity, madder continued to be an important crop in Khiva 
anda valuable source of dyes for local carpet producers. 
The textile boom of the 19
th
century triggered tremendous demand for natural dye 
products. Being a main ingredient of popular Turkey red color, madder root became popular 
11
Shir Muhammad MirabMunis and Muhammad Riza MirabAgahi, Firdaws al-Iqbal: History of Khorezm
Translated from Caghatay and Annotated by Yuri Bregel (Leiden: Brill, 1999), 183
12
Nebol‘sin, StatisticheksiyObozrenie, 341 
13
FedorPichigun, ―O NastoyashempolojeniyaRusskoyTorgovli v SredneyAzii I o BudushixVygodaxotneya,‖ 
Severnaya Pchela, April 6, (1848), 1 
14
Murrey Eiland, ―Problems Associated with the Dissemination of SyntheticDyes in the OrientalCarpet 
Industry,‖International Committee for the History of Technology 5, (1999): 140; Judith Lopez, ―The Transition 
From Natural Madder to Synthetic Alizarin in the American Textile Industry, 1870-1890,‖(PhD diss., Iowa State 
University, 1898), 19-20 
15
In 1891 Khiva exported more than 700 poods of madder root to Turkestan, see MDAf-3, op-1, d-47, 1-12
16
Alexander Kuhn‘s archive in IOM RAS, f-33, op-1, d-96, 2 


27 
product among textile manufacturers. Its cultivation technique prevailed in Russia, the Caucasus 
and the Middle East. Khiva was responding to this global demand by introducing the crop to 
local peasants and cultivating it massively as a cash crop. It soon became one of the main crops 
that the khanate cultivated in its expanding irrigational fields and became the biggest madder 
producer in the region.It shows that, the authorities and merchants in Khiva were well aware of 
the dynamics of the global trade in Eurasian continent and actively involved in it by benefiting 
from increasing demand for dyes. 

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