Causes and prevention of fi re
139
8.1.5 Chemical and LPG (hazardous materials)
The Chemicals (Hazards Information and Packaging for
Supply) Regulations classify substances representing
certain hazards. If a substance has been classifi ed
under CHIP as being dangerous for supply, anyone sup-
plying it must conform to the requirements concerning
the provision of hazard information to those who may
subsequently come in contact with it.
Until the CHIP
Regulations were brought in the only legal requirement
covering the provision of information on dangerous sub-
stances from the supplier was contained in section 6 of
the HSWA, where suppliers were required to pass ‘rele-
vant information’ to customers.
The exact nature of this information was never
elaborated upon, so the CHIP Regulations were
introduced to fi ll this gap, leaving the suppliers and
customers in no doubt as to the information required to
be provided to users.
The CHIP Regulations lay down requirements for the
packaging and labelling of these dangerous chemicals.
The packaging requirements
are straightforward, requir-
ing only that the container for these types of substances
shall be suitable for their contents, and shall be sealed
when supplied.
The labelling requirements are that a package
containing a dangerous substance or preparation bear a
label of an approved design, and be of a specifi c size
relative to the size of the package,
containing relevant
information.
The classifi cations of dangerous substances under
CHIP 2002 are illustrated in Table 8.1.
Fires that involve chemicals and LPG are generally caused
by inadequate arrangements for their safe use, transporta-
tion, storage and disposal. The lack of appropriate levels
of training (and where appropriate levels of supervision)
when using chemicals may lead to reactive chemicals
being mixed causing a fi re or explosive cocktail, or allow-
ing the release of fl ammable vapours which can fi nd an
ignition source to start a fi re.
Mishandling or poorly con-
necting LPG gas cylinders can have a similar effect.
LPG gas cylinders can represent a serious risk if
they are involved in fi re and although they are less often
seen as the direct cause of a fi re they can produce
devastating effects when involved. Poorly maintained
equipment and installations are also seen as a signifi -
cant risk when using LPG and can cause a release that
can in turn result in a fi re or explosion.
Poor storage and transportation arrangements
are also responsible for causing fi res involving both
chemicals and LPG. Storing chemicals such as cleaning
agents which may include
acids and oxidisers in the
same cupboard may precipitate a reaction if leakages
and poor storage arrangements allow the chemicals to
come into contact with one another.
The same can be said of disposal arrangements
when substandard procedures allow reactive chemicals,
fl ammable mixtures and LPG cylinders to come into
contact with sources of ignition or with other reactive
chemicals.
Fires can also start from poorly planned dismantling
or disposal of equipment containing residues of fl amma-
ble liquids or when dealing with spillages as part of
environmental spill protection procedures.
Explosive
Solid, liquid, pasty or gelatinous substances
and preparations which may
react exothermically without atmospheric oxygen thereby quickly evolving gases,
and which under defi ned test conditions detonate, quickly defl agrate or upon
heating explode when partially confi ned.
Oxidising
Substances and preparations which give rise to a highly exothermic reaction
in contact with other substances, particularly fl ammable substances.
Extremely
Liquid substances and preparations having an extremely low fl ash point
fl ammable
and a low boiling point and gaseous substances and preparations which are
fl ammable in contact with air at ambient temperature and pressure.
Highly
The following substances and preparations, namely –
fl ammable
(a) Substances and preparations which may become hot and fi nally catch fi re
in contact with air at ambient temperature without any application of energy,
(b) Solid substances and preparations which may readily catch fi re after brief
contact with a source of ignition and which continue
to burn or to be consumed
after removal of the source of ignition,
(c) Liquid substances and preparations having a very low fl ash point, or
(d) Substances and preparations which, in contact with water or damp air, evolve
extremely
fl ammable gases in dangerous quantities.
Flammable
Liquid substances and preparations having a low fl ash point.
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