Membrane Gas Separation



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206. Membrane Gas Separation

230
400
 – 
60
Cooling water, t/h
38
38
64
99
Investment, $ millions
1.12
0.91
2.03
2.66
Installation area, m 
2
8
5
60
120
Metrics
Energy intensity, kJ/kg H 
2
2808
2738
5760
4853
Mass intensity, kg/kg H 
2
136
133
277
342
Productivity/footprint, kg 

2
/(h m 
2
)
35
58
3.9
2.4


Membrane Engineering: Progress and Potentialities in Gas Separations
309
As can be seen, the energy intensity of the membranes system, for both the temperature 
values considered, is lower than that of the other two processes. This means that the 
energy required for producing a fi xed amount of hydrogen is, in any case, signifi cantly 
lower than that required by the other operations. Also the addition of the steam and 
cooling water is at least half of that necessary for the traditional systems. The productivity 
to footprint ratio calculated for the membrane technology is very interesting in the process 
intensifi cation logic. Considering the same area occupied by the unit, the membrane 
systems show more than tenfold higher productivity.
References 
(1) Advanced Prism ® membrane systems for cost effective gas separations, http://www.
airproducts.com/NR/rdonlyres/81FB384C - 3DB5 - 4390 - AED0 - C2DB4EEDDB18/0/
PrismPGS.pdf .
(2) F. Dautzenberg , M. , Mukherjee , Process intensifi cation using multifunctional reactors , Chem. 
Eng. Sci. , 56 , 251 – 267 ( 2001 ).
(3) A. Stankiewicz , J. A. Moulijn , Process intensifi cation , Ind. Eng. Chem. Res. , 41 ( 8 ), 1920 –
1924 ( 2002 ).
(4) J. C. Charpentier , Process intensifi cation, a path to the future , Ing. Quim. (Madrid), 38 ( 434 ), 
16 – 24 ( 2006 ).
(5) R. W. Baker , Membranes for vapor/gas separation, (2006). http://www.mtrinc.com/publications/
MT01%20Fane%20Memb%20for%20VaporGas_Sep%202006%20Book%20Ch.pdf .
(6) W. J. Koros , R. Mahajan , Pushing the limits on possibilities for large - scale gas separation: 
which strategies? J. Membr. Sci. , 175 , 181 – 196 ( 2000 ).
(7) W. J. Koros , I. Pinnau , Membrane formation for gas separation processes , in Polymeric 
gas separation membranes , D. R. Paul , Y. Yampolskii , (Eds.); CRC Press : Boca Raton, FL
( 1994 ).
(8) B. D. Freeman , Basis of permeability/selectivity trade - off relations in polymeric gas separation 
membranes , Macromolecules , 32 , 375 ( 1999 ).
(9) L. M. Robeson , Correlation of separation factor versus permeability for polymeric membranes . 
J. Mem. Sci. , 62 , 165 – 171 ( 1991 ).
(10) R. W. Baker , Future directions of membrane gas separation technology , Ind. Eng. Chem. Res. , 
41 , 1393 – 1404 ( 2002 ).
(11) P. Bernardo , E. Drioli , Golemme G. , Membrane gas separation. A review/state of the art , Ind. 
Eng. Chem. Res. , DOI: 10.1021/ie8019032 • Publication Date (Web): 22 April 2009 .
(12) T. C. Merkel , B. D. Freeman , R. J. Spontak , Z. He , I. Pinnau , P. Meakin , A. J. Hill , 
Ultrapermeable, reverse - selective nanocomposite membranes . Science , 296 , 519 – 524 ( 2002 ).
(13) S. Hess , C. S. Bickel , R. N. Lichtenthaler , Propene/propane separation with copolyimide 
membranes containing silver ions. , J. Membr. Sci. , 275 , 52 – 59 ( 2006 ).
(14) M. B. H ä gg , T. - J. Kim , B. Li , Membrane for separating CO 
2
and process for the production 
thereof, WO Patent 2005089907 ( 2005 ).
(15) T. - J. Kim , B. Li , M. B. H ä gg , Novel fi xed - site - carrier polyvinylamine membrane for carbon 
dioxide capture . J. Polym. Sci., Part B: Polym. Phys. , 42/43 , 4326 – 4332 ( 2004 ).
(16) www.nanoglowa.com .
(17) R. Dittmeyer , V. H ö llein , K. Daub , Membrane reactors for hydrogenation and dehydrogena-
tion processes based on supported palladium , J. Mol. Cat. A: Chem. , 173 , 135 – 184 ( 2001 ).
(18) J. Caro , M. Noack , P. Kolsch , R. Schafer , Zeolite membranes – state of their development 
and perspective . Micropor. Mesopor. Mater. , 38 , 3 – 16 ( 2000 ).
(19) M. Yang , B. D. Crittenden , S. P. Perera , H. Moueddeb , J. A. Dalmon , The hindering effect 
of adsorbed components on the permeation of a non - adsorbing component through a micro-
porous silicalite membrane: the potential barrier theory . J. Membr. Sci. , 156 , 1 – 9 ( 1999 ).



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