Organik kimyo



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Bog'liq
Organika. Dr.Axmedoff

Tishchenko reaksiyasi.


3CH3-CHO + (C2H5)3Al → 3CH3-COOC2H5 + AlH3


  1. Nesmyenov reaksiyasi. Alkinlarga HgCl2 tasiri. CH3-CCH + HgCl2 → CH3-CCl=CH-HgCl

  2. Sabatye reaksiyasi. Alkenlarni gidrogenlab alkan olish reaksiyasini kashf etgan. CnH2n + H2 CnH2n+2

CH2 = CH2 + H2 → CH3 – CH3

  1. Nyulends reaksiyasi. C2H2 ni 80 oC da CuCl va NH4Cl katalizatorligida vinil atsetilen oladi.

HCCH + HCCH → H2C=CH-CCH

  1. Favorskiy reaksiyasi -alkinlarni izomerlanishni kashf etgan. Katalizator NaOH ning spirtli eritmasi.

CH3-CH2-C≡CH (NaOH spirt ert) → CH3CCCH3 CH3-C(CH3)-CCH → CH3-C(CH3)=C=CH2

  1. Vyurs - Fittig reaksiyasi orqali

Cl C2H5


+ 2Na + Cl-C2H5

+ 2NaCl


etil benzol



  1. Dils-Alders reaksiyasi – 1,3-diyenlarning xona haroratida akrolein (CH2=CH-CHO), mallein angidrid (CH2CO)2O, vinil xlorid (CH2=CHCl), etilen (C2H4), bilan 1,4-birikish reaksiyasiga kirishadi.

CH2

CH2=CH-CH=CH2 +CH2CH-CHO→CH CH-CHO CH CH2

CH2





CH2-CH-CH=CH2 + CH2=CHCl → CH

CH-Cl
CH CH2


CH2



  1. Rezenmud reaksiyasi. Karbon kislotaning xlor angidridlarini qaytarib aldegidlar olish mumkin.

R – COCl + H2 → R – CHO + HCl
CH3 – COCl + H2 → CH3 – CHO + HCl

  1. Reppe reaksiyasi. Alkenlarni is gazi va vodorod yordamida qaytarib aldegid olish. R – CH=CH2 + CO + H2 → R – CH2-CH2-CHO

CH2=CH2 + CO + H2 → CH3-СH2-CHO


  1. N.A. Emmanuel reaksiyasi. so’ngi yillarda uglevodorodlar, masalan, butan, penta va hakozolarni yuqori temperaturada havo kislorodi tasirida oksidlab, sirka kislota olishning sanoat usullarini ishlab chiqqan.

2C4H10 + 5O2 → 4CH3COOH + 2H2O

  1. Meer reaksiyasi - To’yingan uglevodorodlarning gologenli xosilalariga nitrit kislota tuzlari ta'sir ettirib nitrobirikmalar olish.

CH3 - CH2 - J + AgNO2 CH3 - CH2 - NO2 + AgJ

  1. Gofman reaksiyasi. kislota amidlari natriy gipoxlorid yoki gipobromidlar tasirida birlamchi aminlar hosil qiladi.

R - CO - NH2 + 2NaOH + NaClO RNH2 + Na2CO3 + NaCl + H2O

  1. V.M.Rodionov usuli bo’yicha malon kislotadan betta aminokislotalar olish R-CHO + CH2(COOH)2 + NH3 → R-CH(NH2)-CH2-COOH + CO2 + H2O

ORGANIK MODDALAR NOMLARI




Moddalar nomlari

Formulasi (tuzilishi)

1,2,3-trioksibenzol

C6H3(OH)3

1,2,4-trioksibenzol

C6H3(OH)3

1,2-dioksibenzol

C6H4(OH)2

1,3,5-trioksibenzol

C6H3(OH)3

1,3-dioksibenzol

C6H4(OH)2

1,4-dioksibenzol

C6H4(OH)2

2metil propan dikislota

HOOC-CH(CH3)-COOH

2-metil propanal

CH3CH(CH3)CHO

2-metil propanol-2

CH3C(CH3)2OH

2-metilpropanol-1

CH3-CH(CH3)-CH2OH

3,3-dimetilbutin-1

Н3С-С(CH3)2-С≡СН

3-metil-pentin-1

Н3С-CH2-СH(CH3)-С≡СН

4-metil-pentin-1

Н3С-СH(CH3)-CH2-С≡СН

4-metilpentin-2

Н3С-СH(CH3)-С≡С-CH3







Addipin kislota

HOOC-(CH2)4-COOH

Adenin

C5H5N5

Akril amid

CH2=CH-CO-NH2

Akril kislota

CH2=CH-COOH

Akrilonitril

СH2=CH-CN

Akrolein

CH2=CH-CHO

Alanin

CH3-CH(NH2)-COOH

Aldol

CH3-CH(OH)-CH2-CHO

Alizarin

C14H6O2(OH)2

Allen

CH2=C=CH2

Allil spirt

CH2=CH-CH2OH

Allil xlorid

CH2=CH-CH2Cl

Amigdalin

C20H27O11N∙H2O

Amil spirti

C5H11OH

Anabazin

C10H14N2

Antratsen

C14H10

Antraxinon

C14H8O2

Araxidon kislota

CH3(CH2)4CH=CHCH2CH=CHCH2CH=CHCH2CH=CH(CH2)7COOH

Araxin kislota

CH3-(CH2)18-COOH

Asalari mumi (palmitin kilslotaning miritsil efiri)

C15H31COO-C31H63

Asetanilid

C6H5-CH2-NH2

Aseton (dimetil keton)

CH3-CO-CH3

Aseton oksimi

CH3-C(CH3)=N-OH

Asetonfenilgidrazoni

CH3C(N-NH-C6H5)-CH3

Asetonitril

CH3-CN

Azelain kislota

HOOC-(CH2)7-COOH







Benzil radikali

C6H5CH2

Benzil xlorid

C6H5CH2Cl

Benzilamin

C6H5-CH2-NH2

benzilidin radikali

C6H5-CH=

Benzol

C6H6



Benzoxinon

C6H4O2

Benzoy kislota

C6H5COOH

Biuret

NH2-CO-NH-CONH2

Bromoform

СHBr3

Butan

C4H10

Butanal

СH3CH2CH2CHO

Butanol-1

CH3-CH2-CH2-CH2OH

Butanol-2

CH3-CH2-CH(OH)-CH3

Buten-1

CH2 = CH – CH2 – CH3

Buten-2

CH3 – CH = CH – CH3

Buten-2-al

CH3-CH=CH-CHO

Butil asetat

CH3-COOC4H9

Butil spirti

C4H9OH

Butilenglikol

C4H8(OH)2

Butin-1

CH3 – CH2 – C ≡ C H

Butin-2

CH3 – C ≡ C – CH3







Chumoli aldegid

HCHO

Chumoli kislota

HCOOH

Chumoli kislota amidi

CHONH2







D-alanin

CH3-CH(NH2)-COOH

Dekan

C10H22

Dekanal

C9H19CHO

Dekstrin

(C6H10O5)m



Detsen

C10H20

D-fruktoza

CH2OH-CHOH-CHOH-CHOH-CO-CH2OH

D-galaktoza

CH2OH-CHOH-CHOH-CHOH-CHOH-CHO

D-glukoza

C6H12O6

Diasetil selluloza

C6H7O2(OH)(OCOCH3)2

Diaseton spirt

CH3-C(CH3)OH-CH2-CO-CH3

Dietil efir

C2H5-O-С2H5

Dietil keton

C2H5-CO-C2H5

Difenil efir (fenetol)

C6H5-O-C6H5

Diizopropil keton

(CH3)2CH-O-CH(CH3)2

Dimetil efir

CH3-O-CH3

Dimetil rux

(CH3)2Zn

Dimetiletilamin

(CH3)2-N-C2H5

Dinitriladdipin kislota

NC-(CH2)4-CN

Dinitroselluloza

C6H7O2(OH)(ONO2)2

Dioksan

CH2 – CH2
O O
CH2 – CH2

Dioksin

C4H4O2

Dipropil keton

C3H7-CO-C3H7

D-ksiloza

C5H10O5

D-mannit

CH2OH-CHOH-CHOH-CHOH-CHOH-CH2OH

D-manno shakar kislota

HOOC-CHOH-CHOH-CHOH-CHOH-COOH

D-mannon kislota

CH2OH-CHOH-CHOH-CHOH-CHOH-COOH

D-mannoza

C6H12O6



D-mannoza

CH2OH-(CHOH)4-CHO

Dodekan

C12H26

Dodetsilamin

C12H25-NH2

Dulsit

CH2OH-CHOH-CHOH-CHOH-CHOH-CH2OH

Durol

1,2,4,5-(CH3)4C6H2







Elaidin k-ta (olein kislotaning trans izomeri)

CH3-(CH2)7-C-H
||
H-C-(CH2)7-COOH

Enant aldegid

C6H13CHO

Enant kislota

C6H13COOH

Etan

C2H6

Etanal

CH3CHO

Etanol

CH3-CH2-OH

Etanol kislota

CH2OH-COOH

Eten

CH2 = CH2

Etil asetat

CH3-COOC2H5

Etil izopropil efir

C2H5-O-CH(CH3)2

Etil propil efir

C2H5-O-C3H7

Etilamin

C2H5-NH2

Etilbenzol

C6H5C2H5

Etilen xlorgidrin

ClCH2-CH2OH

Etilendiamin

NH2-CH2-CH2-NH2

Etilenglikol

CH2OH-CH2OH

Etin

HC ≡ CH



Eykozan

С20H42







Fenil radikali

C6H5 -

fenilen radikali

C6H4=

Fenol

C6H5OH

Floroglutsin

C6H3(OH)3

Fumar k-ta (trans- izomer)

HOOC-C-H
||
H-C-COOH

Furan

C4H4O







Galaktoza

C6H12O6

Geksadekan

C16H34

Geksadekanal

C15H31CHO

Geksametilbenzol

C6(CH3)6

Geksametilen tetraamin

C6H12N4

Geksametilendiamin

NH2-(CH2)6-NH2

Geksametilendisiloksan

(CH3)3-Si-O-Si-(CH3)3

Geksan

C6H14

Geksanal

C5H11CHO

Geksanol-1

CH3СH2CH2CH2CH2CH2OH

Geksaxlor siklogeksan

C6H6Cl6

Geksaxloran

C6H6Cl6

Geksen

C6H12



Geksil spirit

C6H13OH

Geksin

C6H10

Geksin-1

Н3С-(СH2)3-С≡СН

Geksin-2

Н3С-(СH2)2-С≡С-CH3

Geksin-3

Н3С-СH2-С≡С-C2H5

Geksit

CH2OH-(CHOH)4-CH2OH

Geksoza

C6H12O6

Geptadekan

C17H36

Geptakozan

C27H56

Geptakozan

C27H56

Geptan

C7H16

Geptanal

C6H13CHO

Gepten

C7H14

Geptoza

C7H14O7

Gidroxinon

C6H4(OH)2

Gippur kislota

С6H5CONH-CH2-COOH

Glikokol

NH2CH2-COOH

Glikol

CH2OH-COOH

Glikol aldegid

HOCH2-CHO

Glikol kislota

CH2OH-COOH

Glioksal

CHO-CHO

Glitserin

CH2OH-CHOH-CH2OH

Glitserin aldegid

HOCH2-CHOH-CHO

Glitsin

NH2CH2-COOH

Glukon kislota

CH2OH-CHOH-CHOH-CHOH-CHOH-COOH

Glukoza

C6H12O6



Glutar kislota

HOOC-(CH2)3-COOH

Guanin

C5H5ON5

Guttapercha (poliizoprenni trans holati)

-CH2 H CH3 CH2- C=C С=С

СH3 CH2 – CH2 H n









Imidazol

C3H4N2

Indol

C8H7N

Itakon kislota

COOH
|
H2C=C-CH2-СOOH

Izodurol

1,2,3,5-(CH3)4C6H2

Izokraton k-ta

H-C-CH3

|| HOOC-C-H



Izoleysin (α-amino 3 metil pentan kislota)

C2H5-CH(CH3)-CH((NH2)-COOH

Izomoy aldegid

CH3CH(CH3)CHO

Izomoy kislota

CH3CH(CH3)COOH

Izoniazid

C6H7N3O

Izopropilbenzol

C6H5CH(CH)3







Kalsiy karbit

CaC2

Kapril aldegid

C7H15CHO

Kapril kislota

C7H15COOH




Kaprin aldegid

C9H19CHO

Kaprin kislota

C9H19COOH

Kapron aldegid

C5H11CHO

Kapron kislota

CH3-(CH2)4-COOH

Karbamid

NH2-CO-NH2

Karbinol

CH3OH

Karbol kislota

C6H5OH

Kodaverin (pentametilendiamin)

NH2-(CH2)5-NH2

Kofein

C8H10O2N4

Korbamin kislota

O=C(OH)NH2

Kraton aldegid

CH3-CH=CH-CHO

Kraton k-ta

H-C-CH3
||
H-C-COOH

Kraxmal

(C6H10O5)n

Ksilil

C6H4C2H5

Kumil

C6H4C3H7







Laktamlar

CH2 – CH2 - CH2
NH2- CO

Laktoza

C12H22O11

L-alanin

CH3-CH(NH2)-COOH

L-arabinoza

C5H10O5

Laurin kislota

C11H23COOH

Levulin aldegid

CH3-CO(CH2)2-CHO



Leysin kislota (α-amino izokapron kislota)

CH3-CH(CH3)-CH2-CH(NH2)-COOH

Lignatserin kislota

CH3-(CH2)22-COOH

Limon kislota

HOOC-CH2-C(OH)(COOH)-CH2-COOH

Linol kislota

CH3-(CH2)4-CH=CH-CH2-CH=CH-(CH2)7-COOH

Linolein kislota

CH3CH2CH=CHCH2CH=CHCH2CH=CH(CH2)7COOH

Linolen k-ta

C2H5CH=CHCH2CH=CHCH2CH=CH(CH2)7COOH







Magniy metilyodid

CH3MgJ

Malein k-ta (sis-izomer)

H-C-COOH
||
H-C-COOH

Mallon kislota

HOOC-CH2-COOH

Maltoza

C12H22O11

Margarin kislota

CH3-(CH2)15-COOH

Metaakril k-ta

CH3=C(CH3)-COOH

Metan

CH4

Metanal

HCHO

Metanol

CH3OH

Metil amin

CH3-NH2

Metil butil efir

CH3-O-C4H9

Metil etil efir

CH3-O-C2H5

Metil etilketon

CH3-CO-C2H5

Metil geksadetsilketon

CH3-CO-C16H33

Metil ikkilamchi butil efir

CH3-O-CH(CH3)C2H5



Metil izobutil efir

CH3-O-CH2-CH(CH3)2

Metil izopropil efir

CH3-O-CH(CH3)2

Metil izopropil keton

CH3-CO-CH(CH3)2

Metil mallon kislota

HOOC-CH(CH3)-COOH

Metil propil efir

CH3-O-C3H7

Metil propil keton

CH3-CO-C3H7

Metil uchlamchi butil efir

CH3-O-C(CH3)3

Metilenxlorid

CH2Cl2

metiletilamin

CH3-NH-C2H5

Metiletilmallon kislota

HOOC-C(CH3)(C2H5)-COOH

Metilnatriy

CH3Na

Metiltetradetsil keton

CH3-CO-C14H29

Metilxlorid

CH3Cl

Miristin kislota

CH3-(CH2)12-COOH

m-ksilol

C6H4(CH3)2

Mochevina

NH2-CO-NH2

Mononitroselluloza

C6H7O2(OH)2ONO2

Moy aldegid

СH3CH2CH2CHO

Moy kislota

C3H7COOH

Moykislota amidi

CH3-(CH2)2-CONH2

Mukon k-ta

HOOC-CH=CH-CH=CH-COOH







Naftalin

C10H8

Natriy etileat

C2H5ONa

Natriy fenolyat

C6H5ONa



Nikotin

C10H14N2

Nikotin kislota

C5H4NCOOH

Nitrobenzol

C6H5NO2

Nitroetan

C2H5NO2

Nitrogeksan

C6H13NO2

Nitrozamin

(C6H5)2N=NO

Nonadekan

C19H40

Nonakozan

C29H60

Nonan

C9H20

Nonanal

C8H17CHO

Nonen

C9H18







Oksalat (shovul) k-ta

HOOC-COOH

Oksazol

C3H3ON

Oksigidroxinon

C6H3(OH)3

o-ksilol

C6H4(CH3)2

Oksimetiletilketon

CH3-C=(NOH)-C2H5

Oksimoy kislota

CH3-CH2-CHOH-COOH

Oksinitril

CH2=CH-CN

Oksipropion kislota

CH3-CHOH-COOH

Oktadekan

C18H38

Oktadekanal

C17H35CHO

Oktakozan

C28H58

Oktan

C8H18

Oktanal

C7H15CHO



Okten

C8H16

Olein kislota

CH3-(СH2)7-CH=CH-(CH2)7-COOH

Olma kislota

HOOC-CH2-CHOH-COOH

Oppanol

Poliizobutilaen C4H8

Organik shisha

[-CH2-C(CH3)-COOCH3]

o-xlor toluol

C6H4CH3Cl







Palmitin aldegid

C15H31CHO

Palmitin kislota

C15H31COOH

Palmiton

C15H31-CO-C15H31

Palmitoolein kislota

CH3(CH2)5-CH=CH-(CH2)5-COOH

Paraform

(HCHO)n

Patoka

Dekstrin bilan glukoza aralashmasi

Pellargon aldegid

C8H17CHO

Pellargon kislota

CH3-(CH2)7-COOH

Pentadekan

C15H32

Pentakozan

C25H52

Pentametilbenzol

C6H(CH3)5

Pentan

C5H12

Pentanal

C4H9CHO

Pentanol-1

СH3CH2CH2CH2CH2OH

Penten

C5H10

Pentilenglikol

C5H10(OH)2

Pentin-1

НС≡С-(СН2)2-СН3

Pentin-2

Н3С—С≡С—С2Н5



Pentoza

C5H10O5

Pikramid

C6H2(NO2)3NH2

Pikrin kislota

C6H2OH(NO2)3

Pimelin k-ta

HOOC-(CH2)5-COOH

Piran

C5H6O

Pirazin

C4H4N2

Piridin

C5H5N

Piridoksal

C8H9O2N

Piridoksamin

C8H12O2N2

Piridoksin

C8H11NO2

Pirimidin

C4H4N2

Pirogallol

C6H3(OH)3

Pirokatexin

C6H4(OH)2

Pirrol

C4H5N

Pirrolidin

C4H9N

Pirrolin

C4H7N

p-ksilol

C6H4(CH3)2

Polibutadiyen

[-CH2-CH=CH-CH2-]

Poliizopren

[-CH2-CH=C(CH3)=CH2

Prenitol

1,2,3,4-(CH3)4C6H2

Probka k-ta

HOOC-(CH2)6-COOH

Propan

C3H8

Propanal

C2H5CHO

Propanol-1

CH3-CH2-CH2OH

Propanol-2

CH3-CH(CH3)OH



Propanol-2 kislota

CH3-CHOH-COOH

Propantriol-1,2,3

CH2OH-CHOH-CH2OH

Propen

CH2 = CH – CH3

Propil spirti

C3H7OH

Propilamin

C3H7-NH2

Propilbenzol

С6H5C3H7

Propilenglikol

C3H6(OH)2

Propin

HC ≡ C – CH3

Propion aldegid

C2H5CHO

Propion kislota

C2H5COOH

Purin

C4H4N4

Putressin (tetrametilendiamin)

NH2-(CH2)4-NH2









Qaxrabo kislota

HOOC-(CH2)2-COOH

Qaxrabo kislota angidridi

(CH2CO)2O







Rezorsin

C6H4(OH)2

Riboza

C5H10O5







Sebasion k-ta

HOOC-(CH2)8-COOH

Selluloza ksantogenati

C6H7O2(OH)2(O-CS-SNa)

Seyze tuzi

K[C2H4PtCl3]∙H2O

Shakar kislota

HOOC-(CHOH)4-COOH




Shilliq kislota

HOOC-(CHOH)4-COOH

Siangidrin

CH3-C(OH)CN-CH2-COO-С2H5

Siklobutan

C4H8

siklogeksan

С6H12

Siklogeksanol

C6H11OH

Siklogeksanon

C6H10O

Siklogeptan

C7H14

Siklooktan

C8H16

Siklopentan

C5H10

Siklopropan

C3H6

Sintez gazi

CO∙2H2

Sirka aldegid

CH3CHO

Sirka kislota

CH3COOH

Sirka kislota amidi

CH3-CONH2

Sirka kislota oksimi

CH3CH=N-OH

Sirka kislota xlorangidridi

CH3-CClO

Sitozin

C4H5ON3

Siydik kislota

C5H4O3N4

Stearin aldegid

C17H35CHO

Stearin kislota

С17H35COOH

Stirol (vinil benzol)

C6H5CH=CH2

Sulfanil kislota

NH2-C6H4-SO3H

Surik

Pb3O4

Sut kislota

CH3-CHOH-COOH







Teflon

Politetraftoretilen (C2F4)n



Tetradekan

C14H30

Tetrametil silan

Si(CH3)4

Tetroza

C4H8O4

Tiazol

C3H3NS

Timin

C5H6O2N2

Tiofen

C4H4S

Tiofos

C10H14O5SPN

Tiopiran

C5H6S

Tiozin

C4H5SN

tolil

C6H4CH3

Toluidin

CH3-C6H4-NH2

Toluol

C6H5CH3

Triakontan

C30H62

Triasetilselluloza

C6H7O2(OCOCH3)3

Tridekan

C13H28

Trietil alyuminiy

(C2H5)3Al

Trimetil fosfin

P(CH3)2

Trimetilenglikol

CH2OH-CH2-CH2OH

Trimetilsilanol

(CH3)3SiOH

Trinitroglitserin

CH2ONO2-СHONO2-CH2ONO2

Trinitroselluloza

C6H7O2(ONO2)3

Trioksimetilen

(CH2-O)3

Trioza

C3H6O3







Uglerod (IV)-xlorid

CCl4



Undekan

C11H24

Undekan kislota

C10H21COOH

Uratsil

C4H4O2N2

Urotropin

C6H12N4







Valerian aldegid

C4H9CHO

Valerian kislota

C4H9COOH

Valin kislota

CH3CH(CH3)-CH-COOH

Vinil asetilen

HCC-CH=CH2

Vinilpropion k-ta

CH2=CH-(CH2)2-COOH

Vinilsirka k-ta

CH2=CH-CH2-COOH

Vino spirti

C2H5OH

Vistaneks

Poliizobutilaen C4H8

Vitamin-B6

C8H11O2N

Vitamin-PP

C6H6N2O







Xinolin

C9H7N

Xlor trimetil silan

(CH3)3SiCl

Xloralgidrat

Cl3C-CH(OH)2

Xlordimetil fosfin

(CH3)2P-Cl

Xloroform

CHCl3

Xlorofos

C4H8O2Cl3P

Xloropren

CH2=CH-C(Cl)=CH2

Xlorpiridin

C5H4NCl









Yodoform

CHJ3

yog’och spirti

CH3OH

γ-oksimoy kislota laktami

CH2 - CH2 CH2 С=O

O








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