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Science without borders - 2020 ★ Volume 14



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Science without borders - 2020 ★ Volume 14
Typical conditions that determine the corrosion of the equipment of circulating 
systems are the following:
1.Cooling of recycled water in cooling towers by spray contributes to its 
saturation with oxygen, water circulation in turn provides a good flow of oxygen to the 
metal surface, and as a result, favorable conditions for corrosion with oxygen 
depolarization are created.
2.Due to the evaporation of water in cooling towers or other cooling devices, 
the concentration of salts in the cooling water increases, accompanied by an increase 
in its aggressiveness.
3.Recycled water can be contaminated with impurities from specific industries.
4.Due to the shortage of river water, it is possible to use waste water from some 
industries to feed the recycling cycles.
5.Heat transfer surfaces are made of various metals, and the temperature 
gradient in different places of the turnover cycle is not uniform.
6.The corrosion process is associated with the phenomena of thermal stability 
and biogenicity.
It should be noted that the last two factors have a special effect on the corrosion 
aggressiveness of recycled water. The presence or absence of carbonate deposits and 
the action of microorganisms are the reason that often the means used to protect against 
corrosion of condensation and refrigeration equipment in water recycling systems do 
not give satisfactory results [4]. Deposits of calcium and magnesium carbonates protect 
the metal from corrosion. At the same time, thickened layers of carbonate deposits on 
the metal surface cause a decrease in heat transfer, which is unacceptable. The tendency 
to form carbonate deposits on the surface of ferrous metals in recycled water can be 
determined by the index of water saturation with calcium carbonate (Langelier index):
J = p H - pHs
where, p H - actual concentration of hydrogen ions in water;
pHs - concentration of hydrogen ions in water that is equably saturated with 
calcium carbonate [4].
D. 
G. Yakovlev shows that at J=0 water is stable, at J > 0 there is a tendency to 
form J = 0,74 at a total concentration of Cl- and SO42- equal to 0,4 g/l, it allows to 
maintain a 0,5 mm thick pellicle of CaCO3, and the rate of corrosion is reduced to 0,05
g/m2h.
168



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