Termin
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O’zbek tilidagi sharhi
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Rus tilidagi
sharhi
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Ingliz tilidagi sharhi
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Organik kimyo
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uglerod saqlagan birikmalarning kimyosi
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Organicheskaya ximiya – ximiya soedineniy ugleroda
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Organic chemistry the study of carbon
compounds.
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Gomolog
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gomologik qatorining vakili
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Gomolog – predstavitelь gomologicheskogo ryada
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Homolog a member of homologous series
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Gomologik qator
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bir necha CH2 guruhi bilan farqi bo’lgan birikmalarning qatori
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Gomologicheskiy ryad - ryad soedineniy, v kotorom kajdыy posleduyuщiy
predstavitelь otlichaetsya ot predыduщego na gruppu SN2.
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Homologous series a family of compounds in which each member differs from the next by one methylene group
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Radikal
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bitta elektron yo’q bo’lgan guruh (atom)
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Radikal – gruppa atomov ili atom bez odnogo elektrona
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Radical a species that has an odd number of electrons
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Izomerlar
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sifat va miqdor jihatdan bir xil tarkibga ega bo’lgan faqat kimyoviy yoki fazoviy tuzilishi bilan farq qiladigan, shunga ko’ra xossalari ham har xil bo’lgan birikmalar
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Izomerы – soedineniya s odinakovыm elementnыm sostavom, molekulyarnoy massoy, no otlichayuщiesya stroeniem.
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Isomers compounds that have the same
molecular formula but different structures.
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Fazoviy izomerlar (stereoizomer-lar)
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tarkibi va kimyoviy tuzilishi bir xil bo’lgan faqat fazoda atomlarning o’zaro joylashishi bilan bir-biridan farq qiladigan birikmalar
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Prostranstvennыe izomerы (stereoizomerы) – soedineniya s odinakovыm sostavom i ximicheskim stroeniem, no otlichayuщiesya po raspolojeniyu atomov v prostranstve.
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Stereoisomers isomers that have their atoms connected
in the same order but have different three-dimensional
arrangements.
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Konfiguratsiya
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molekuladagi atomlarning fazoda malum tartibda joylashishi
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Konfiguratsiya – to ili inoe otnositelьnoe
raspolojenie atomov molekulы
v prostranstve.
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Configuration the three-dimensional arrangement
of atoms bonded to a chirality center.
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Konformatsiya
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ma’lum bir konfiguratsiyaga ega bo’lgan molekula ichida atomlarning yoki atom guruhlarning bir yoki bir necha σ-bog’ atrofida aylanishidan hosil bo’ladigan holat
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Konformatsiya - razlichnoe prostranstvennoe raspolojenie atomov
ili atomnыx grupp v molekulax opredelennoy konfiguratsii, obuslovlennoe vraщeniem
vokrug σ-svyazey.
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Conformations the three-dimensional shape of a
molecule at any given instant, assuming that rotation around
single bonds is frozen.
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Boshlang’ich struktura
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birikmaning eng ko’p sonli xarakteristik guruhlar birikkan kismi
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Rodonachalьnaya struktura - strukturnыy fragment molekulы, lejaщiy
v osnove nazvaniya.
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Skeletal structures a shorthand way of writing structures in which carbon atoms are assumed to be at each
intersection of two lines (bonds) and at the end of each line.
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Funksional guruh
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birikmaning kimyoviy xossalarni beradigan xarakteristik guruh
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Funktsionalьnaya gruppa
- strukturnыy fragment molekulы, opredelyayuщiy yee ximicheskie svoystva.
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Functional an atom or group of atoms that is part of a larger molecule and has a characteristic chemical reactivity.
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Kovalent bog’lanish
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umumiy elektron juftlar asosida vujudga keladigan metallmaslar orasidagi bog’lanish.
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Kovalentnaya svyazь – svyazь, obrazovannaya za schet obщix elektronnыx par.
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Covalent bond a bond formed by sharing electrons
between atoms.
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Ion bog’lanish
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elektrostatik tortishuv asosida vujudga keladigan bog’lanish
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Ionnaya svyazь – svyazь, obrazovannaya za schet elektrostaticheskogo prityajeniya atomov
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Ionic bond the electrostatic attraction between
ions of unlike charge.
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Induktiv effekt
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elektron bulutlarining -bog’ bo’yicha siljishi
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Induktivnыy effekt – smeщenie elektronov po -svyazi
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Inductive effect the electron-attracting
or electron-withdrawing effect transmitted through s bonds.
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Nitrolash
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organik modda tarkibiga nitroguruh (-NO2) ni kiritish reaksiyasi
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Nitrovanie - vvedenie nitrogruppы (-NO2) v sostav organicheskogo soedineniya
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Nitration the substitution of a nitro group onto
an aromatic ring.
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Sulfolash
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organik modda tarkibiga sulfoguruh (–SO3H) ni kiritish reaksiyasi
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Sulьfirovanie –vvedenie sulьfogruppы
(–SO3H) v sostav organicheskogo soedineniya
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Sulfonation the substitution of a sulfonic acid
group ( -SO3H) onto an aromatic ring.
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Oksidlanishi
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birikma molekulasining kislorod atomi bilan o’zaro reaksiyasi
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Okislenie – reaktsiya molekulы soedineniya i kisloroda s umenьsheniem stepeni okisleniya ugleroda.
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Oxidation a reaction that causes a decrease in electron ownership by carbon, either by bond formation between carbon and a more electronegative atom (usually oxygen, nitrogen,
or a halogen) or by bond-breaking between carbon and a less electronegative atom (usually hydrogen).
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Karboksillash
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CO2 bilan o’zaro reaksiyasi
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Karboksilirova-nie – reaktsiya s SO2
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Carboxylation the addition of CO2 to a molecule.
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Dekarboksillash
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CO2 ajralishi bilan boradigan reaksiyasi
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Dekarboksiliro-vanie – reaktsiya otщepleniya SO2
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Decarboxylation the loss of carbon dioxide from
a molecule. -keto acids decarboxylate readily on heating.
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Degitratlanish
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H2O ajralishi bilan boradigan reaksiyasi
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Degidratatsiya - reaktsiya s otщepleniem N2O
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Dehydration the loss of water from
an alcohol to yield an alkene.
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Degidrogalogen-lash
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vodorod va galogen ajralishi bilan boradigan reaksiyasi
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Degidrogalogenirovanie - reaktsiya s otщepleniem vodoroda i galogena
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Dehydrohalogenation the loss of HX from
an alkyl halide. Alkyl halides undergo dehydrohalogenation to
yield alkenes on treatment with strong base.
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sp3-gibridlanish
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bitta s- va uchta p-elektronlarning orbitallarining gibridlanishi va to’rtta yangi gibridlangan bulutlar hosil bo’lishi
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sr3-Gibridizatsiya -
obrazovanie iz odnoy s- i trex r-orbitaley chetыre kachestvenno novыe,
ravnotsennыe orbitali
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sp3 hybrid orbitals hybrid orbitals derived by combination
of an s atomic orbital with three p atomic orbitals.
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sp2-gibridlanish
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qo’shbog’dagi uglerod atomida bitta s- va ikkita p-orbitallar gibridlanib, uchta tenglashgan orbitallarni hosil qilishi
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sr2-Gibridizatsiya -
obrazovanie iz odnoy s- i dvux r-orbitaley tri kachestvenno novыe,
ravnotsennыe orbitali
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sp2 hybrid orbitals hybrid orbitals derived by combination
of an s atomic orbital with two p atomic orbitals.
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sp-gibridlanish
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bitta s- bilan bitta p-orbital bir-biri bilan «aralashib» ikkita gibridlangan orbitalarni hosil qilishi
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sr-Gibridizatsiya -
obrazovanie iz odnoy s- i odnoy r-orbitali dve kachestvenno novыe,
ravnotsennыe orbitali
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sp hybrid orbitals hybrid orbitals derived from the
combination of an s and a p atomic orbital.
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Gomolitik parchalanish
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molekulani tashkil etuvchilarni A va B deb faraz qilsak, ular orasida bog’ hosil qilishda ishtirok etadigan elektron jufti ikki tashkil etuvchi (molekula) o’rtasida bo’linadi.
A:B A∙ + B∙
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Gomoliticheskiy razrыv – razrыv svyazi v xode kotoroy kajdыy atom imeet po odnomu elektronu
A:B A∙ + B∙
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Homolytic bond breakage the kind of bondbreaking
that occurs in radical reactions when each fragment
leaves with one bonding electron: A:B A∙ + B∙
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Geterolitik parchalanish
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bunda A va B tashkil etuvchilar orasidagi umumiy elektron juftini shu tashkil etuvchilardan biri tortib oladi.
A:B A+ + :B-
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Geteroliticheskiy razrыv – razrыv svyazi v xode kotoroy odin atom imeet paru elektronov, drugoy atom ne imeet
A:B A+ + :B-
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Heterolytic bond breakage the kind of bondbreaking
that occurs in polar reactions when one fragment
leaves with both of the bonding electrons:
A:B A+ + :B-
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Elektrofil (elektronni yoqtiraman)
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musbat zaryadli ion.
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Elektrofil («lyublyu elektron»)– polojitelьno zaryajennыy ion
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Electrophile an “electron-lover,” or substance that
accepts an electron pair from a nucleophile in a polar bondforming
reaction.
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Nukleofil
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manfiy zaryadli ion
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Nukleofil («lyublyu nuklon»)– otritsatelьno zaryajennыy ion
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Nucleophile an electron-rich species that donates
an electron pair to an electrophile in a polar bond-forming reaction.
Nucleophiles are also Lewis bases.
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Alkanlar
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tarkibida oddiy σ-bog’lar tutgan, umumiy formulasi CnH2n+2 bo’lgan uglevodorodlar
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Alkanы - uglevodorodы, v molekulax kotorыx atomы
ugleroda svyazanы prostыmi kovalentnыmi σ-svyazyami. CnH2n+2
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Alkanes a class of compounds of carbon and
hydrogen that contains only single bonds.
CnH2n+2
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Sikloalkanlar
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umumiy formulasi SnH2n bo’lgan, faqat zanjiri uglerod atomlaridan tarkib topgan yopiq xalqali uglevodorodlar
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Alkanы - uglevodorodы, v molekulax kotorыx atomы
ugleroda svyazanы prostыmi kovalentnыmi σ-svyazyami. CnH2n+2
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Cycloalkane an alkane that contains a ring of
carbons.
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Alkenlar
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tarkibida bitta qo’shbog’ saqlagan, umumiy formulasi CnH2n bo’lgan, birikish reaksiyalariga kirishadigan to’yinmagan uglevodorodlar
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Alkenы - uglevodorodы, v molekulax kotorыx atomы
ugleroda svyazanы dvoynoy svyazьyu. CnH2n
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Alkene a hydrocarbon that contains a
carbon–carbon double bond,
R2C=CR2
CnH2n
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Markovnikov qoidasi
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nosimmetrik tuyinmagan uglevodorodlarga galoidvodorodlarni birikkanda vodorod ko’p vodorod tutgan uglerod atomiga borib birikadi
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Pravilo Markovnikova -
pri vzaimodeystvii galogenovodorodov
s nesimmetrichnыmi
alkenami atom vodoroda prisoedi-nyaetsya k bolee gidrogenizovanno-mu atomu ugleroda,
to yestь atomu ugle-roda, soderjaщemu
bolьshee chislo atomov vodoroda.
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Markovnikov’s rule in the addition of HX to an alkene, the hydrogen atom bonds to
the alkene carbon that has fewer alkyl substituents.
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Zaytsev qoidasi
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degitratlanich reaksiyalarda vodorod kam gidrogenlangan uglerod atomidanketadi
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Pravilo Zaytseva –v reaktsiyax otщep-leniya vodы vmeste s gidroksilom uxodit atom vodoroda ot menee gidrogenizi-
zirovannogo sosed-nego atoma ugleroda.
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Zaitsev’s rule a rule stating that E2 elimination
reactions normally yield the more highly substituted alkene as
major product.
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Alkinlar
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tarkibida bitta uch bog’ saqlagan, umumiy formulasi CnH2n-2 to’yinmagan uglevodorodlar
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Alkinы - uglevodorodы, v molekulax kotorыx atomы
ugleroda svyazanы troynoy svyazьyu. CnH2n-2
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Alkyne a hydrocarbon that contains a
carbon–carbon triple bond, RC≡CR.
CnH2n-2
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Aromatik uglevodorodlar (arenlar)
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molekulasida benzol xalqasi saqlagan karbosiklik birikmalar.
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Arenы – soedineniya, soderjaщie benzol
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Arene an alkyl-substituted benzene.
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Aromatiklik
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halqasi bo’lgan birikmalar birikish reaksiyalariga qiyinchilik bilan, almashinish reaksiyalariga osonlik bilan kirish xodisasi, elektronlarning soni 4n + 2 formulaga mos kelgan
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Aromatichnostь - sovokupnostь spe-tsificheskix svoystv
benzola, a imenno vыsokaya stabilь-nostь, inertnostь v reaktsiyax prisoedi-neniya i sklonnostь k reaktsiyam zameщe-niya, kolichestvo r-elektronov sootvet-stvuet formule
4n + 2
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Aromaticity
the special characteristics
of cyclic conjugated molecules, including unusual stability and a
tendency to undergo substitution reactions rather than addition
reactions on treatment with electrophiles. Aromatic molecules
are planar, cyclic, conjugated species with 4n + 2 p electrons.
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Alkilgalogenli hosilalari
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alifatik uglevodorod molekulasidagi bir yoki bir necha vodorod atomlarining galogenga almashinishidan hosil bo’lgan birikmalar
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Alkilgalogenidы – alifaticheskie soedineniya, v kotorыx odin ili neskolьko atomov vodorodы zameщenы na atom galogena.
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Alkyl halide a compound with a halogen
atom bonded to a saturated, sp3-hybridized carbon atom.
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Bimolekulyar nukleofil o’rin olish reaksiyasi (SN2)
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bir bosqichda, oraliq aktiv kompleks hosil bo’lishi bilan boradigan va reaksiyaning tezligi ikkita zarrachaning: galogen hosilaning va nukleofilning konsentratsiyasiga bog’liq bo’ladigan reaksiyasi
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Reaktsiya SN2 - reaktsiya proisxodit v odnu stadiyu cherez obrazovanie perexodnogo sostoyaniya,
v postroenii kotorogo prinimaet uchastie kak molekula galogenalkana, tak
i nukleofilьnыy reagent.
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SN2 reaction a bimolecular nucleophilic substitution
reaction.
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Monomolekulyar nukleofil o’rin olish reaksiyasi (SN1)
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ikki bosqichli, reaksiyaning tezligi faqat galogen hosilaning konsentratsiyasiga bog’liq bo’ladigan va bunda galogen hosila dissotsiyalanishidan so’ng o’rin olish reaksiyasi amalga oshadigan reaksiyasi
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Reaktsiya SN1 – reaktsiya gde razrыv svyazi C-Hal predshestvuet obrazovaniyu
svyazi C-Nu.
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SN1 reaction a unimolecular nucleophilic
substitution
reaction.
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Spirtlar
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uglevodorodlardagi bir yoki bir necha vodorod atomlarining gidroksil hosil bo’lgan birikmalar.
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Spirtы - proizvodnыe alifaticheskix uglevodorodov, v kotorыx odin ili neskolьko atomov vodoroda zameщenы na –ON gruppu
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Alcohols a class of compounds with -OH group bonded to a saturated, sp3-hybridized carbon,
ROH.
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Fenollar
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benzol xalqasidagi bir yoki bir necha vodorod atomining gidroksil guruhga almashinishidan hosil bo’lgan birikmalar
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Fenolы -proizvodnыe aromaticheskix uglevodorodov, v kotorыx odin ili neskolьko atomov vodoroda zameщenы na –ON gruppu
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Phenols a class of compounds with
an -OH group directly bonded to an aromatic ring, ArOH.
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Oddiy efirlar
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spirt gidroksilidagi vodorod atomining boshqa radikalga almashinishidan hosil bo’lgan birikmalar
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Prostыe efirы – proizvodnыe spirtov, v kotorыx vodorodo gidroksilьnoy gruppы zameщen na radikal
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Ethers a class of compounds that has two organic substituents bonded to the same oxygen atom,
ROR
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Aldegidlar
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molekulasi tarkibida aldegid guruh saqlagan oksobirikmalar
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Alьdegidы – soedineniya, soderjaщie karbonilьnuyu gruppu i vodorod
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Aldegides a class of compounds
with organic substituents bonded to a carbonyl
group. RCON
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Ketonlar
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molekulasi tarkibida keto guruh (R-C=O) saqlagan oksobirikmalar
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Ketonы – soedineniya, soderjaщie dva radikala i karbonilьnuyu gruppu
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Ketones a class of compounds
with two organic substituents bonded to a carbonyl
group, R2C=O.
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Aminlar
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ammiakning bir yoki bir necha vodorod atomlarinig uglevodorod radikallariga almashinishidan hosil bo’lgan organik birikmalar
RNH2, R2NH, R3N.
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Aminы – proizvodnыe ammiaka, v kotorыx odin ili neskolьko atomov vodorodы zameщenы na radikalы
RNH2, R2NH, R3N.
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Amines
a class of compounds containing
one or more organic substituents bonded to a nitrogen
atom, RNH2, R2NH, or R3N.
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Diazobirikmalar
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tarkibida bir-biri bilan o’zaro bog’langan azot atomlari tutgan va bu azot atomlardan biri uglevodorod radikali, ikkinchisi mineral kislota qoldig’i bilan bog’langan organik birikmalar
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Diazosoedineniya – soedineniya obщey formuloy RN2X.
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Diazo compounds a class of compounds with the
general structure RN2X.
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Azobirikmalar
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tarkibida azoguruh -N=N- saqlagan va bu guruhdagi azot atomlari aromatik uglevodorod radikallari bilan bog’langan organik birikmalar
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Azosoedineniya – soedineniya obщey formuloy R-N=N-R
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Azo compounds
a class of compounds with the
general structure R-N=N-R.
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Karbon kislotalar
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tarkibida karboksil guruh (-COOH) saqlagan birikmalar
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Karbonovыe kislotы - soedineniya, soderjaщie karboksilьnuyu gruppu
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Carboxylic acids, RCO2H
compounds
containing the
-CO2H functional group.
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Aminokislotalar
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karboksil va aminoguruh saqlovchi organik birikmalar
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Aminokislotы - soedineniya, soderjaщie i karboksilьnuyu i aminogruppu
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Amino acids
a type of difunctional compound
with an amino group on the carbon atom next to a carboxyl
group, RCH(NH2)CO2H.
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Laktam
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siklik amid
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Laktam – tsiklicheskiy amid
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Lactams cyclic amides.
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Lakton
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siklik efir
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Lakton – tsiklicheskiy efir
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Lactones cyclic esters.
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Amidlar
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karboksil guruhdagi gidroksil guruhning aminoguruhga almashingan karbon kislota hosilalari.
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Amidы – proizvodnыe karbonovыx kislot, imeyuщie gruppu
-CONR2
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Amides
a class of compounds containing
the -CONR2 functional group.
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Geterohalqali birikmalar
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halkasida uglerod atomlaridan boshqa element atomi saqlagan yopiq zanjirli birikmalar.
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Geterotsiklы – tsiklы, imeyuщie v svoem sostave otlichnыy ot ugleroda atom
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Heterocycle a cyclic molecule whose ring
contains more than one kind of atom.
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Enantiomerlar
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ko’zgu tasvirini beradigan stereoizomerlar.
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Enantiomerы – stereoizomerы, yavlyayuщiesya zerkalьnыm otobrajeniem drug druga
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Enantiomers stereoisomers of a chiral substance
that have a mirror-image relationship. Enantiomers have opposite
configurations at all chirality centers.
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Diastereomerlar
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ko’zgu tasvirini bermaydigan stereoizomerlar.
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Diastereomerы - stereoizomerы, ne yavlyayuщiesya zerkalьnыm otobrajeniem drug druga
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Diastereomers non–mirror-image stereoisomers;
diastereomers have the same configuration at one or more chirality
centers but differ at other chirality centers.
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Epimerlar
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bitta asimmetrik atomi konfiguratsiyasi bilan farq qiladigan stereoizomerlar
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Epimerы - diastereoizomerы, otlichayuщiesya po konfiguratsii odnogo atoma ugleroda
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Epimers diastereomers that differ in configuration
at only one chirality center but are the same at all others.
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Mutarotatsiya
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monosaxaridlarning yangi tayyorlangan eritmasining qutblangan nur sathini burish burchagining qiymati ma’lum vaqtgacha o’zgarish xodisasi
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Mutarotatsiya – izmenenie znacheniya ugla udelьnogo vra-щeniya s techeniem vremeni v sveje-prigotovlennыx rastvorax monosaxaridov
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Mutarotation the change in optical rotation
observed when a pure anomer of a sugar is dissolved in water.
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Glikozidlar
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monosaxaridlarning
poluatsetal gidroksil gruppalari bilan biron organik radikal bog’lanishi bilan hosil bo’lgan birikmalar
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Glikozidы - proiz-vodnыe monosaxari-dov, poluchennыe v rezulьtate vzaimo-deystviya poluatse-talьnogo gidroksi-la s drugimi organicheskimi soedineniyami
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Glycoside a cyclic acetal formed by reaction of a
sugar with another alcohol.
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Lipidlar
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o’simlik va hayvon to’qimalaridan qutblanmagan erituvchilar yordamida ajratib olinadigan birikmalar
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Lipidы - obshirnaya gruppa prirodnыx organicheskix
soedineniy, glavnыm obrazom proizvodnыx vыsshix alifaticheskix kislot
i spirtov.
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Lipids naturally occurring substances
isolated from cells and tissues by extraction with a nonpolar solvent.
Lipids belong to many different structural classes, including
fats, terpenoids, prostaglandins, and steroids.
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