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LNG carriers are used when the transport distance does not justify the cost
of a pipeline. The main drawback is
the cost of the liquefaction, calculated as
how much of the total energy content of the gas is used for liquefaction.
About 6% of energy content is used to produce LNG in a large modern plant,
due to overall thermal efficiency. More than 10% could be consumed with
smaller, gas turbine-driven trains. This compares to losses of about 0.9% per
1,000 km of transport distance for large pipeline systems.
Melkøya LNG Plant with LNG Carrier Arctic Princess Photo: Statoil
The LNG feedstock comes from a gas plant as outlined above. It must
satisfy sales gas specifications. Ethane,
propane and butane all have
freezing points of less than -180 °C and can be part of the LNG, but the
concentration of methane is generally above 90%. Some NGLs are also
needed as refrigerant for the cryogenic process.
5.5.1 LNG liquefaction
LNG processes are generally patented by large engineering,
oil and gas
companies, but are generally based on a one- two- or three-stage cooling
process with pure or mixed refrigerants. The three main process types of
LNG process with some examples of process licensors are:
• Cascade
cycle:
o
Separate
refrigerant
cycles with propane, ethylene and
methane (ConocoPhillips)
• Mixed refrigerant cycle:
o
Single mixed refrigerant (SMR) (PRICO)
o
Single mixed refrigerant (LIMUM
®
) (Linde)
o
Propane pre-cooled mixed refrigerant: C3MR (sometimes
referred to as APCI: Air Products & Chemicals, Inc.)
o
Shell dual-mixed process (DMR) (Shell)
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o
Dual mixed refrigerant (Liquefin Axens)
o
Mixed fluid cascade process (MFCP) (Statoil/Linde)
• Expander
cycle
o
Kryopak
EXP
®
process
Each process has different characteristics in scalability, investment cost and
energy efficiency.
For smaller installations, e.g., to handle stranded gas or
isolated small gas fields, a single cycle process is preferable due to its low
CAPEX (and possibly lower weight for floating LNG), even if energy
efficiency is significantly lower than the best cascade or DMR processes,
which cost more but also allow
the largest trains typically, 7.8 million tons per
annum and lowest energy consumed per energy unit LNG produced.
Most processes use a mixed refrigerant (MR) design. The reason is that the
gas has a heat load to temperature (Q/T)
curve that, if closely matched by
the refrigerant, will improve stability, throughput and efficiency (see
the figure
below). The curve tends to show three distinct regions, matching the pre-
cooling, liquefaction and sub-coiling stages. The refrigerant gas composition
will vary based on the individual design, as will the power requirement of
each stage,
and is often a patented, location-specific combination of one or
two main components and several smaller, together with careful selection of
the compressed pressure and expanded pressure of the refrigerant, to
match the LNG gas stream.
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