«Mahalliy xomashyolar va ikkilamchi resurslar asosida innovatsion texnologiyalar»

Фойдаланилган адабиётлар 
1. Эшқурбонов Ф.Б, Эрмуратова Н.А. Болтаев Н.С., Бўриев С., Нуралиев Ғ.Т 
Диглицидилтиокарбамид ва меламин асосидаги ионит ва унинг металл ионлари 
билан ҳосил қилган комплекс бирикмаларининг иқ-спектроскопик тадқиқоти // 
Академик А.Ғ.Ғаниевнинг 90 йиллигига бағишланган “Аналитик кимё 
фанининг долзарб муаммолари” VI Республика илмий-амалий анжумани, -2020, 
147-б 
2. Эшқурбонов Ф.Б Янги самарали комплекс ҳосил қилувчи ионитлар синтези, 
уларнинг нодир ва ноёб металлар сорбциясида қўлланилиши// диссертацияси 
Т-2019 
3. Тураев Х.Х, Йулчиева М.Г., Чориева Н.Б. , Касимов Ш.А., Эрмуратова Н.А. 
Таркибида азот ва кислород бўлган комплекс ҳосил қилувчи сорбент синтези
Академик А.Ғ.Ғаниевнинг 90 йиллигига бағишланган “Аналитик кимё 
фанининг долзарб муаммолари” VI Республика илмий-амалий анжумани, -
Термиз, 3-5 май, -2020. -265-б 

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174 
STUDY OF THERMAL ANALYSIS OF SILICON-CONTAINING
PHTHALOCYANINE PIGMENT 
Turayev X.X., 
 
Shukurov D.X., Ko’charov I.A., Mamarasulova K.I.,
Termiz davlat universiteti 
The metal-containing phthalocyanines have been used traditionally on an 
industrial scale for many years. They have long been used as dyes and pigments, 
especially in colored printing inks, as pigments in paints, plastics, metal structures, 
and as one of the main materials for dyeing synthetic fibers. Phthalocyanines form 
organometallic compounds (metal coordination complexes) just like plant 
chlorophylls. They exhibit good thermal and chemical stability and also have 
extensive optical and electronic properties that can be improved as a result of 
synthetic modifications such as attaching functional groups around their molecules. 
Macrocyclic molecules based on metallic and nonmetallic phthalocyanines are 
very thermally and chemically stable and can contain the following most metals (e.g., 
Li, Cu, Zn, Co, Mn, Fe, and nonmetallic Si, H) phthalocyanins. Organic 
semiconductor devices based on a large number of heterostructures are being 
intensively studied today due to the simplicity of production technology, the 
possibility of using flexible substrates in their production and their relative 
cheapness. These organic semiconductor phthalocyanins are sensitive to light, 
resulting in photoane titanium dioxide TiO
2
in the manufacture of dye-sensitive solar 
cells (DSSC) and other (OFET) i.e. electronic devices. is used in conjunction with 
liquid electrolytes to form a micro-layer on materials [1]. 
Silicon-containing phthalocyanine is a more intense pigment than other metal-
containing phthalocyanine complexes and has been shown to be sensitive to light by 
analysis on a V-5000 Spectrophotometer. In the future, this phthalocyanine complex 
will be widely used in dye-sensitive solar cells [2]. Because, it has the property of 
transmitting charge and absorbing the visible light spectrum well. Solar panels, which 
are sensitive to dyes in the literature today, are also called Gratsel cells. Rutin-based 
complex substances are used as dyes [3]. Since this dye is economically expensive 
and its preparation process is very complicated, we used silicon phthalocyanine 
pigment as an alternative to routine dyes. Silicon-preserved phthalocyanine pigment 
differs from rutinic pigment in that it has a high assimilation coefficient, is 
environmentally friendly and inexpensive.
Thermal analysis of the new silicon-containing phthalocyanine (SiPc) pigment 
was performed in the temperature range of 20–500 °C. The resulting derivatogram is 
shown in Figure-1 and consists of 4 curves. Analysis of the differential 
thermogravimetric analysis curve (DTGA) (curve 2) shows that the DTGA curve 
occurs mainly in 2 intensive decomposition temperature ranges. Decomposition range 
1 corresponds to a temperature of 53-254°C, and decomposition range 2 corresponds 
to a temperature of 258-479 °C. 

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