Kimyo fakulteti 3-kurs kimyo yo‘nalishi talabalariga v-semestr uchun «Organik kimyo»

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Propanal hamda propanonning fosforpentaxlorid bilan amalga oshuvchi reaksiya tenglamalarini yozing (hosila, di-,

				gem-, aldegid, keton, galogen).
202	1	20	20	Galoformlar olish reksiyalariga misollar yozing (hosila, galogen, aldegid, etanol, atseton, ishqor, di-).
203	1	20	20	Etanoldan foydalanib yodoform olish reaksiya tenglamasini yozing (spirt, laboratoriya, kristal, soda, sariq, surkov moyi).
204	3	20	20	Etanoldan foydalanib yodoform olish reaksiya mexanizmini yozing (spirt, aldegid, yod, gidroksil, nukleofil, kristall, soda, sariq).
205	1	21	21	Butenning monoxlorli hosilasini izomerlarini yozing va nomlang (holat, skelet, trans, sis, qo‟shbog‟).
206	1	21	21	Pentenning monoxlorli hosilasini izomerlarini yozing va nomlang (holat, skelet, trans, sis, qo‟shbog‟).
207	2	21	21	Vinilxloridda electron siljishlarni tushintiring (induktiv, mezomer, musbat, manfiy, σ, π-sistema, bo‟linmagan, juft, electron, C-Cl).
208	2	21	21	Vinilxloridning gidrogalogenlanish reaksiya tenglamasini yozing va maxsulotni hosil bo‟lishida oraliq ionning ahamiyatini izohlang (kabkation, barqaror, ta‟sir, electron, birikish, elektrofil, terminal).
209	2	21	21	Allilxloridda elektron siljishlarni tushintiring (induktiv, mezomer, musbat, manfiy, σ, π-sistema, bo‟linmagan, juft, electron, C-Cl, dissitsiatsiya, qaytar).
210	2	21	21	Allilxloridning natriygidroksid bilan boradigan reaksiya tenglamasini yozing va maxsulotni hosil bo‟lishida oraliq ion hamda sharoitning ahamiyatini izohlang (monomolekulyar, bimolekulyar, kabkation, barqaror, ta‟sir, electron, birikish, elektrofil).
211	1	22	22	Tarkibi C8H9Br fоrmulaga mоs keluvchi mоnоgalоidli arоmatik birikmalarning izоmerlarini yozing va ularning nоmlang (aromatic halqa, holat, o‟rinbosar, skelet, toluol).
212	1	22	22	Tarkibi C7H7Br fоrmulaga mоs keluvchi mоnоgalоidli arоmatik birikmalarning izоmerlarini yozing va ularning nоmlang (aromatic halqa, holat, o‟rinbosar, skelet, toluol).
213	1	22	22	Benzolni AlCl3 ishtirokida to‟la xlorlanish reaksiya tenglamasini yozing va mahsulotni nomlang (almashinish, Lyuis, katalizator).
214	1	22	22	Geksaxloran 300-400^oC da qizdirilganda qanday galogen hosila hosil bo‟ladi? Reaksiya tenglamasini yozing va mahsulotni nomlang (elimerlanish, harorat, katalizator, HCl).
215	1	22	22	Toluolni Lyuis katalizatori va hv ta‟sirida bromlanish reaksiya tenglamalarini yozing (almashinish, kompleks, π-, σ-, elektrofil, radikal, yon zanjir, aromatik halqa).
216	2	22	22	Propilbenzolni hv ta‟sirida bromlanish reaksiya tenglamasini yozing va mahsulotni hosil bo‟lishini tushintiring (radikal, barqaror, aromatic halqa, π-sistema)
217	2	22	22	2,4-dinitroftorbenzolni C3H7NH2 bilan o‟zaro reaksiya tenglamasini yozing (almashinish, elektronoaktseptor, nukleofil, electron zichlik, δ+).
218	1	22	22	Allilbromidning olinish reaksiyasiga misol yozing (radikal, harorat, alken).
219	3	20	20	2-Brompropanning qutbli aproton erituvchi muhitida

				NaNO2 bilan o‟zaro ta‟sirlashishidan qanday mahsulotlar hosil bo‟ladi? Reaksiya tenglamasini yozing (ambident, SN1, SN2, elektromanfiyligi kata, qutblanuvchanligi kata, markaz).
220	3	21	21	Ushbu sxemani amalga oshiring va qo‟shimcha mahsulotni hosil bo‟lishini Kornblyum qoidasi orqali tushintiring o ^CH^2^CH CH^3^Cl^2^/ 500 C^A^NaCN / DMSOB + (C - qo'shimcha)
221	3	7	7	Propilxlorid misolida Vyurs reaksiyasining mexanizmini yozing. (Radikal anion, radikal, karbanion, metalorganik birikma, almashinish, nukleofil, sinxrom, to‟rtmarkazli)
222	3	7	7	Butilxlorid misolida Vyurs reaksiyasining mexanizmini yozing. (Radikal anion, radikal, karbanion, metalorganik birikma, almashinish, nukleofil, sinxrom, to‟rtmarkazli)
223	3	7	7	Alkilxlorid misolida Vyurs reaksiyasining mexanizmini yozing. (Radikal anion, radikal, karbanion, metalorganik birikma, almashinish, nukleofil, sinxrom, to‟rtmarkazli)
224	2	7	7	Izopropilxloriddan Kori-Xaus reaksiyasi asosida alkanlar olish (Li, Gelman reagenti, Cu(I) tuzi, almashinish, nukleofil)
225	2	7	7	Propilxloriddan Kori-Xaus reaksiyasi asosida alkanlar olish (Li, Gelman reagenti, Cu(I) tuzi, almashinish, nukleofil)
226	2	7	7	Etilxloriddan Kori-Xaus reaksiyasi asosida alkanlar olish (Li, Gelman reagenti, Cu(I) tuzi, almashinish, nukleofil)
227	2	7	7	Butanni Kanovalov va Gess reaksiyalari bo‟yicha nitrolanish tenglamalarini yozing va ikki reaksiyada hosil bo‟ladigan mononitromahsulotlar tuzilishidagi farqni ko‟rsating (alkil, galogenid, Vyurs, Kanovalov, Gess, C-C, C-H, mononitro, asosiy mahsulot)
228	2	7	7	Propanning konformerlarini Nyuman proyektsiyasi bo„yicha tasvirlang hamda konformerlarni energetik jixatdan taqqoslang (konformatsion, superpozitsiya, minimal energiya, konformerlar, barqaror).
229	1	7	7	Geksandab hosil bo‟lishi mumkin bo‟lgan radikallarni IYUPAC nomenklaturasi bo‟yicha nomlang (radikal, -an, - il, uglerod zanjiri).
230	3	8	8	Alkanni nitrolash reaksiya mexanizmini yozing (SR, radikal- zanjir, gomolitik, uzilish, innetsirlanish, usishi, uzilish).
231	1	9	9	1-Brom-2-metibuten-1 da Z va E izomerlarini yozing (Geometrik, vinil vodorodlari, almashingan, to‟tr xil, og‟ir massali, o‟rinbosar, “birgalikda”, “alohida”, qo‟shbog‟ tekisligi).
232	1	9	9	2-Brom-2,3-dimetilpentanning ishqorning spirtdagi eritmasi bilan o‟zaro reaksiya tenglamasini yozing (β-elemerlanish, spirt, ishqor, kuchli asos, trans isomer, asosiy, sis isomer, antikoplanar, sinxron).
233	1	9	9	2-Metilpentanol-2 ning kislotali sharoitda degidratlanishi orqali alken olish reaksiyasining tenglamasini yozing (170^oC, degidratlanish, karbkation, barqaror, kislota-asos reaksiyasi, alken, trans izomer).
234	3	9	9	3-Metilbutanol-2 ning kislotali sharoitda degidratlanish reaksiyasining mexanizmini yozing (170^oC, degidratlanish,

				karbkation, barqaror, kislota-asos reaksiyasi, alken, trans isomer, asosiy, qo‟shimcha, mahsulot).
235	1	9	9	2,3-Dibromdan olefin olish reaksiyasi tenglamasini yozing (Zn, Mg, vetsinal, digalogen, tortib olish, t^o).
236	2	9	9	Vinilxloriddan Kross-birikish reaksiyasi orqali alken olish reaksiya tenglamasini yozing (vinil vodorodi, galogen atomi, almashingan, metalorganik birikma, C-C).
237	1	9	10	Terminal butinni gidroborlash orqali tegishli alken olinish reaksiya tenglamasini yozing (vodorod, bor, sin, Z, isomer, yagona isomer, stereoselektiv).
238	3	9	10	Nosimmetrik alkenga bromning birikish reaksiyasining mexanizmini yozing (Simmetrik ko‟priksimon, ion, trans birikish, treo, eritro, sis, trans, isomer, π-komleks, σ- komleks, limitlovchi, tez, sekin).
239	3	9	10	α,α-dimetiletilenning bromlanish reaksiyasining tenglamasini yozing va hosil bo‟ladigan mahsulotlarni IYUPAC nomenklatura bo‟yicha nomlang (xiral, ratsemat, fazoviy, izomeriya, deastereoizomer).
240	3	9	10	Benzoilperoksidi ishtirokida izobutenning bromsuksinimid bilan bromlanish reaksiya tenglamasini yozing (almashinish, radikal, barqaqror, allil, HBr).
241	1	9	10	Izobutenga kislotali sharoitda C2H5OH ning birikish reaksiya tenglamasini yozing va asosiy mahsulotni belgilang (elektrofil, birikish, oddiy efir, π-komleks, σ-komleks, limitlovchi bosqich, tez, sekin, kabokation, trans, gidrid, ko‟chish).
242	1	9	10	Dimetiletilen ishtirokida amalga oshuvchi Vagner reaksiyasi tenglamasini yozing (muhit, neytral, kuchsiz ishqoriy, glikoll).
243	2	9	10	Buten-1 ni ozonlanish reaksiya tenglamasini yozing. Hosil bo‟lgan ozonidning dimetilsulfoksid ta‟sirida qaysi sinfga mansub mahsulotni hosil qilishini reaksiya tenglamasi orqali ifodalang (ozon, alken, kislorodli organic birikma, vodorod peroksid).
244	1	11	11	Butadiyen asosiy kimyoviy xossalarini uning molekulasini tuzilishi orqali izohlang. (konyugerlangan, tutash, gibridlanish, sistema, C-C, C=C, masofa, 1,2-, 1,4-, sharoit, bog‟liq).
245	1	11	11	Geksadiyen-2,5 ning Z va E izomerlarini yozing hamda nomlang (o‟rinbosar, “bir xil”, “alohida”, qo‟shbog‟, izomeriya, geometrik, konfiguratsion).
246	1	11	11	C5H8 formulasiga ega alkadiyenlarni yozing va nomlang. Ular orasidan geometric izomeriya kuzatiladigan vakillarini ko‟rsating (zanjir, uglerod, qo‟shbog‟, holat, sis, trans, Z, E).
247	2	12	12	Pentadiyen-1,3 misolida alkadiyenlarda sharoitga bog‟liq holda 1,2- va 1,4- birikish reaksiyalariga misollar yozing (elektrofil, allil, karbokation, π-kompleks, σ-komleks, barqaror, knetik, termodinamik, nazorat).
248	2	12	12	Pentadiyen-1,3 ga HBr birikish jarayonida hosil bo‟ladigan allil ionlarini tasvirlang va ularni sharoitga bogliq ravishda jarayonda qatnashishini ko‟rsating. (barqaror, allil, π- sistema, karbokation, termik, knetik, nazorat, tutash,).

249	1	12	12	Geksadiyen-1,3 ni benzoilperoksidi ishtirokida bromlash reaksiyasi tenglamasini yozing va mahsulotni nomlang (radikal, 1,2-, 1,4-, harorat, elektrofil).
250	1	13	13	C8H14 tarkibli asosiy zanjiri 5 ta uglerod atomidan iborat alkin izomerlarini yozing va nomlang (Zanjir, holat, uzun, uglerod zanjiri, yaqin, -in).
251	3	13	13	2,2-dixlorpropandan alkin olish reaksiya mexanizmini yozing (digalogen, ishqor, spirt, tortib olish, asos, antikoplanar, sinxron, ikki marotaba, E2).
252	1	13	13	Butin-1 ni yuqori haroratda (150^oC) spirtli eritmada barqaror alkinga izomerlanishini yozing (KOH, glitserin, terminal, qayta guruhlanish, atsetilen-allen).
253	2	13	13	2,2-dixlorpropanga suyuq ammiakdagi natriy amid ta‟sir ettirib alkinlar olinishiga misollar yozing (Vitsinal, 1,2-, terminal, alkin, asos, kislota-asos reaksiya, harorat, yumshoq, antikoplanar).
254	2	13	13	2,2-dixlorpropanga KOH ning geksandiol-2,5 dagi eritmasi ta‟sir ettirilganda qanday tipdagi alkinlar hosil bo‟ladi? (Vitsinal, terminal, alkin, asos, kislota-asos reaksiya, harorat, yumshoq).
255	2	13	14	Penten-1-in-4 ning tetraxlormetan muhitida bromlanganda 5,6-dibromgeksin-1 hosil bo‟ladi. Ushbu jarayonda qo‟shbog‟ning uch bog‟ga nisbattan selektivligini tushintiring (ionlanish potensiali, YuBMO, nukleofillik, electron, bog‟lanish).
256	2	13	14	Propin-1 ga sirka kislotaning birikish reaksiya tenglamasini yozing va ushbu reaksiyani alkinlarga spirtlarning birikish reaksiyasidan farqlarini ko‟rsating (H3PO4, simob tuzlari, kompleks, nukleofil, elektrofil, efir, oddiy, murakkab, terminal, alkin).
257	2	13	14	Propin bilan etanol, sianid kislota va sirka kislotalarning birikish reaksiya tenglamalarini sharoitlarni ko‟rsatgan holda yozing. Ushbu reaksiyalarni o‟zaro o‟xhsash va farqlarini keltiring (H3PO4, ammiak, Cu2Cl2, simob tuzlari, kompleks, nukleofil, elektrofil, efir, oddiy, murakkab, terminal, alkin)
258	1	13	14	Propinga sirka kislotaning birikish reaksiya tenglamasini yozing va mahsulotni qaysi sinfga mansubligini bayon eting. (efir, vinil, nukleofil, barqaror, beqaror, karbanion, to‟yinmagan).
259	2	15	15	Tsiklopbutanning kimyoviy xossalarini uning tuzilishi orqali tushintiring (gibridlanish, σ-bog‟, alken, alkan, “banansimon”, π-bog‟).
260	1	15	15	Dils-Alder reaksiyasi asosida 1,3-dimetiltsiklogeksan olish reaksiyasini yozing (Tsiklobirikish, elektrosiklik, sinxron, diyenofil, diyen).
261	2	15	15	Etil tsiklogeksanning vanna va kreslo shakllarini yozing. Ularning reaksion qobilyati bilan tuzilishi o‟rtasidagi bog‟liqlikni tushintiring (vanna, kreslo, barqaror, beqaror, aksial, ekvatorial, conformer, superpozitsiya, o‟rinbosar).
262	2	16	16	Siklopropen va siklopropenil karbokationning aromatikligini o‟zaro solishtiring (Xyukel, tutash, sistema, π, masofa,

				koplanar, barqaror, kimyoviy, elektrofil, gibridlanish).
263	2	16	16	C12H18 tarkibli uch o„rinbosarli aromatik uglevodorodning izomerlarini yozing va ularni nomlang (benzol, o‟rinbosar, tuzilish, holat, fenil, alkan, hosila).
264	1	16	16	Tsiklogeksan va geksanni to„la degidrogenlash va degidrosikllash reaksiya tenglamalarini yozing (katalizator, harorat, yuqori, H2O, H2, Zelinskiy, Kazanskiy).
265	1	16	16	Fridel-Krafts usulida propilxlorid ishtirokida aromatic uglevodorod gomologini olish reaksiya tenglamasini yozing (elektrofil, karbokation, Lyuis katalizatori, π-kompleks, σ- komleks, aromatiklik, tez, sekin).
266	2	17	17	Lyuis katalizatori yordamida 3-fenilpentanni bromlash reaksiya tenglamasini yozing. Reaksiyada hosil bo‟ladigan aromatik mahsulotni nomlang (Elektrofil, komleks, π, σ, sekin, tez, aromatiklik, gibrid ion, birikish, ajralish, almashinish, fazoviy, qulay).
267	1	17	17	Toluolning sulfolanish reaksiya tenglamasini yozing (Elektrofil, kontsentrlangan, komleks, π, σ, sekin, tez, aromatiklik, gibrid ion, birikish, ajralish, almashinish, kislota).
268	2	17	17	Toluolning sulfolanish reaksiya mexanizmini yozing (Elektrofil, kontsentrlangan, komleks, π, σ, sekin, tez, aromatiklik, gibrid ion, birikish, ajralish, almashinish, kislota).
269	2	18	18	Naftalinni turli sharoitlarda sulfolanish reaksiya tenglamalarini yozing va ularga mos faollanish energiyalai tasvirlangan diagrammani chizing (almashinish, elektrofil, α, β, nazorat, termodinamik, knetik).
270	3	19	19	Benzolning Etilxlorid yordamida alkillanish reaksiya mexanizmini yozing (almashinish, elektrofil, kompleks, π, σ, gomolog, katalizator).
271	2	7	8	Quyidаgi sхеmаni аmаlgа оshiring va mahsulotni nomlang. CH3CH2COONa + H2O ^elektrolizA ^HNO3 ^(s)P, T B
272	2	9	9	Quyidаgi sхеmаni аmаlgа оshiring va mahsulotlarni nomlang. ^H^2Cl2 Na ^CH3CH HC CH3 Ni, P, T ^Ahv ^B C
273	3	7	8	Quyidаgi sхеmаni аmаlgа оshiring va mahsulotlarni nomlang. 2C7H15Cl 2Na A SO2 + Cl2 hv B ^NaOHC
274	2	8	8	Quyidаgi sхеmаni аmаlgа оshiring va mahsulotlarni nomlang. A elektroliz izobutan ^Cl^2B ^NaC hv
275	3	8	8	Quyidаgi sхеmаni аmаlgа оshiring va mahsulotlarni nomlang. Zn ^Cl2 CH3Cl SO2 +^Cl2 C2H5Br ^A^BZn ^C^D
276	3	7	7	Quyidаgi sхеmаni аmаlgа оshiring va mahsulotlarni nomlang. ^250^0^CA ^Cl^2B CH3Cl C SO2 + Cl2 D CO + H2 Ni hv 2Na
277	3	7	7	Quyidаgi sхеmаni аmаlgа оshiring.

				A + B ^Zn2,2,3-trimetilbutan + HNO3 ^H^2^O P, T
278	2	7	7	Quyidаgi sхеmаni аmаlgа оshiring. ^HBrHNO3 (s) ^A 2-brom-2-metilbutanB
279	3	10	10	Quyidаgi sхеmаni аmаlgа оshiring. + HCl KMnO4 ^CH3 - CH2 - CH^=^CH2^A- HCl B H2O, 0^0C
280	3	9	9	Quyidаgi sхеmаni аmаlgа оshiring. KOH A ^H2O^Al^2^O^3 (CH3)2CHCH2CH2Br spirt, t [H+] ^Bt ^C
281	3	8	8	Quyidаgi sхеmаni аmаlgа оshiring. CH ^Br2A 2Br2 B ^KOHC 3 ^CH2 H2C CH3 CH3 ^hvhv ^spirt,^t
282	3	9	9	Quyidаgi sхеmаni аmаlgа оshiring. ^[H2SO4]^H2^O^[Al2O3]^HOCl CH3 CH CH2 CH2OH t ^A[H+] ^Bt ^C[H+] ^D CH3
283	2	9	9	Quyidаgi sхеmаni аmаlgа оshiring. CH CHClCH Cl ^ZnB ^H^2^OC H2SO4 ^HClE 3 2 t0 t0 ^D
284	3	9	9	Quyidаgi sхеmаni аmаlgа оshiring. Cl2 H2O+Cl2 ^Zn ^CH3-CH=CH2hv ^A^BC
285	2	9	10	Quyidаgi sхеmаni аmаlgа оshiring. 2HBr ^Zn^H2 HOCH2CH2CH2OH ^A B C spirt, t
286	2	9	10	Quyidаgi sхеmаni аmаlgа оshiring. Zn ^[O] ^CH2Br(CH2)4CH2BrA ^B
287	3	11	11	Quyidаgi sхеmаni аmаlgа оshiring. CH2 ^CHCH2 CH2 A Cl2 B CH CH2
288	3	18	18	Quyidаgi sхеmаni аmаlgа оshiring. H2CO / HCl / ZnCl2 A +A, Zn B -Zn(OH)Cl
289	2	18	18	Quyidаgi sхеmаni аmаlgа оshiring. CH3 ^HNO32HNO H^+ KMnO4 ^A^3B C ^H2SO4H2SO4
290	3	9	9	Quyidаgi sхеmаni аmаlgа оshiring. A H2 B^HClC^AgNO2CH CH NO 3 2 2
291	3	8	8	Quyidаgi sхеmаni аmаlgа оshiring.

				CH ^t^katA ^+2A^/ C^aktB ^C2H5ClC [O] D ^4AlCl3
292	2	10	10	Quyidаgi sхеmаni аmаlgа оshiring. Konovalov C Mg C ^H^2^OA ^[H]^B 2 3 Gess D
293	3	10	10	Quyidаgi sхеmаni аmаlgа оshiring. A [H] B ^Cl2C ^NaNO2CH CH NO hv ^3 2 2
294	3	11	11	Quyidаgi sхеmаni аmаlgа оshiring. CaO C A ^H2OB ^H2C HCl D ^NaNO2E
295	3	17	17	Quyidаgi sхеmаni аmаlgа оshiring. C6H6 ^A C6H5Br ^BC6H5CH3 ^CC6H5NO2
296	3	16	16	Quyidаgi sхеmаni аmаlgа оshiring. A B C C6H6  C6H5CH(CH3)2  C6H5CBr(CH3)2  C6H5C(CH3)=CH2
297	3	16	16	Quyidаgi sхеmаni аmаlgа оshiring. CH3CH2Br [O] ^toluol[AlBr3] ^AB
298	2	9	10	Quyidаgi sхеmаni аmаlgа оshiring. O CH2-C O Ca t^0A HCl B ^NaC CH2-C O O
299	2	8	8	Quyidаgi sхеmаni аmаlgа оshiring. elektroliz ^Cl2 Na CH3 ^CH^CH2COONaH2O ^Ahv B C CH3
300	3	8	8	Quyidаgi sхеmаni аmаlgа оshiring. C ^Mg^H2^O C3H7Br ^A^B D

Fakultet dekani. N.Musulmonov

Kafedra mudiri. S.Tillayev

Fan o`qituvchilari. A.Nasrullayev., D.Tuxtayev