Tayyorlangan taqribiy konsentratsiyali KMnO4 ishchi eritmasini shovul kislotasi bo’yicha standartlash
KMnO4 eritmasi konsentratsiyasi boshlang’ich modda bo’lgan shovul kislotasining standart eritmasi yordamida aniqlanadi:
2KMnO4 + 5H2C2O4 + 3 H2SO4 2MnSO4 + K2SO4 + 10CO2 + 8H2O
Ishning borishi:
Titrlash kolbasiga 2 ekvimol H2SO4 eritmasidan 10-15 sm3 silindrda o’lchab quyiladi va qum xammomida 80-90 0S gacha qizdiriladi. Issiq eritmaga pipetka yordamida 10,00 sm3 H2C2O4·2H2O eritmasi o’lchab solinadi va aralashtirilib, KMnO4 eritmasi bilan turg’un pushti rang hosil bo’lgunicha titrlanadi. Titrlash kamida 2 marta olib boriladi. Titrant hajmi byuretkadagi eritmaning sath chizig’i bo’yicha olinadi.
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№
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V H2C2O4, sm3
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V KMnO4, sm3
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1
2
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10,00
10,00
|
|
NH2C2O4 · V H2C2O4 NKMnO4·E KMnO4
NKMnO4 = ------------------------ g.ekv/dm3 ; TKMnO4 = ---------------------- g/sm3
V KMnO4 1000
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