Catalysts reduce the activation energy of reactions and enhance the rate of specific reactions. Therefore they are crucially important in chemical industry, exhaust gas treatment and other chemical reactions



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8.01 Catalytic reactions (1)-converted

Insertion reaction


In the reaction of an alkyl or hydride ligand to shift to a carbonyl or olefin ligand coexisting on the central metal, the resultant complex appears as if a carbonyl or an olefin has inserted between the M-R or M-H bond. This is called an insertion reaction.

Reaction of a coordinated ligand


This is the process in which a coordinated reactant reacts to form a product. By coordinating to a metal, the reactants take geometrically and electronically suitable conformations. It is the basis of catalyst design to control these reaction conditions.

Since a reaction is repeated while the complex used as a catalyst remains unchanged by forming a cycle of reactions, the reactants/complex ratio is very small, coinciding with the definition of a catalyst. The catalytic cycle in hydrogenation of ethylene is illustrated in Figure 8.1.




Figure 8.1.1: - Catalytic cycle of ethylene hydrogenation by the Wilkinson catalyst. L is a ligand and Sol is a solvent molecule.

If the triphenylphosphine ligand P(C6H5)3 in the Wilkinson catalyst is replaced by an optical active phosphine,


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