Part of the problem chemists have
with molecule-based systems is
connecting them to the macroscopic
world. One approach is to modify a
nanocrystalline surface with
supramolecular components. For
example, a ruthenium complex bound
to nanocrystalline titanium dioxide
gives a supramolecular structure that
undergoes photochemically driven
electron- and energy-transfer
processes. This makes them
attractive materials for use in solar
cells20. Supramolecular aggregates of
organic molecules have also been
used to make molecular switches,
whose conductivity is controlled by
the chemical state of the molecule.
Chemical sensors based on such
switches could in theory be used to
detect individual molecules of a
pollutant.
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