Ergashev V.E.
Anorganik kimyodan reaksiyalar to’plami
NaOH(kons.) + HCN = NaCN + H 2O.
6NaOH(suyul.) + 4F2 = OF2↑ + 6NaF + O2↑ + 3H2O.
2NaOH(kons., sovuq) + E 2 = NaEO + NaE + H 2O (E = Cl, Br, I) 6NaOH(kons., issiq) + 3E 2 = NaEO3 + 5NaE + H 2O.
12NaOH(kons., issiq) + 5Cl 2 + Br2 = 2NaBrO3 + 10NaCl + 6H2O.
2NaOH + 2Na = 2Na 2O + H2 (600 ºC).
4NaOH + 3Ca = 3CaO + Na 2O + 2Na + 2H 2 (600 ºC).
2(NaOH∙H2O) + 2Al = 2NaAlO 2 + 3H2 (400 – 500 ºC)
2NaOH(kons.) + 6H 2O(issiq) + Al = 2Na[Al(OH) 6] + 3H2↑.
2NaOH(kons.) + 2H 2O + Zn = Na2[Zn(OH)4] + H2↑.
NaOH(suyul.) + EO 2 = NaHEO3 (E = C, S)
2NaOH(kons.) + EO 2 = Na2EO3 + H2O.
4NaOH(kons.) + SiO2
Na4SiO4 + 2H2O,
2NaOH + SiO 2 = Na2SiO3 + H 2O (900 – 1000 ºC).
4NaOH + 6NO = 4NaNO 2 + N2 + 2H 2O (350 – 400 ºC).
4NaOH(issiq) + 4NO 2 + O2 = 4NaNO3 + 2H2O.
NaOH + Al 2O 3 = 2NaAlO2 + 2H 2O (900 – 1100 ºC),
NaOH + Al(OH)3 = NaAlO2 + 2H 2O (1000 ºC). NaOH(kons.) + Al(OH) 3 = Na[Al(OH)4].
2NaOH(kons.) + Zn(OH) 2 = Na2[Zn(OH)4] (20 ºC).
NaOH(kons.) + NH4Cl(kons.) = NaCl + NH3↑ + H2O (qaynash.).
2NaOH(suyul.) + FeI2 = 2NaI + Fe(OH) 2↓ (N2 atmosferasidada), 2NaOH(suyul.) + 2AgNO 3 = Ag 2O↓ + H 2O + 2NaNO 3.
3NaOH(suyul.) + AlCl 3 = Al(OH)3↓ + 3NaCl, 4NaOH(kons.) + AlCl 3 = Na[Al(OH)4] + 3NaCl.
2NaOH(suyul.) + ZnCl 2 = Zn(OH) 2↓ + 2NaCl, 4NaOH(kons.) + ZnCl 2 = Na2[Zn(OH)4] + 2NaCl.
4NaOH(s) elektroliz4Na(katod) + O2↑(anod) + 2H2O.
K – KALIY
1. 2K + 2H2O = 2KOH + H2↑.
2K + 2HCl(suyul.) = 2KCl + H2↑.
8K + 6H2SO4(suyul.) = 4K2SO4 + SO2 + S↓ + 6H2O (H2S qo’shimchasi),
21K + 26HNO 3(suyul.) = 21KNO3 + NO↑ + N 2O↑ + N 2↑ + 13H2O.
4. 2K + 2KOH = 2K2O + H2 (450 ºC).
5. 2K + H2 = 2KH (200 – 350 º).
K + O2(havo) = K2O (ёнdiриш, K2O2 qo’shimchasi),
K O2 K O ↓
O2 ,KO ↓ (– 50 ºC, suyuq NH
da),
2 2 2 3
4K + O2 + 2H2O = 4KOH.
8. 2K + E2 = 2KE (20 ºC, E = F, Cl, Br, I).
9. 2K + E = K2E (100 – 200 ºC, E = S, Se, Te).
3K + P(qizil) = K3P(yashil) (200 ºC, Ar atmosferasida).
2K + 2H2S(to’yingan) = 2KHS↓ + H2↑ (benzolda). 12. 2K + 2NH3(g) = 2KNH2 + H2 (65 – 105 ºC).
KH – KALIY GIDRID
1. 2KH = 2K + H2 (400 ºC, vak.).
KH + H2O = KOH + H2↑.
KH + HCl(suyul.) = KCl + H2↑.
4. 2KH + O2 = 2KOH (t > 200 ºC).
5. KH + Cl2 = KCl + HCl (400 – 450 º).
6. KH + CO2 = K(HCOO) (t ≤ 150 ºC, p).
7. 4KH + 3SiO2 = 2K2SO3 + Si + 2H2 (500 ºC).
8. KH + NH3(g) = KNH2 + H2 (300 ºC).
K2O – KALIY OKSID
1. 2K2O = K2O2 + 2K (350 – 430 ºC).
K2O + H2O = 2KOH.
K2O + 2HCl(suyul.) = 2KCl + H2O.
4. K2O + CO2 = K2CO3 (400 ºC).
5. K2O + 2NO2 = KNO2 + KNO3 (150 – 200 ºC).
6. K2O + Al2O3 = 2KAlO2 (1000 ºC).
t
7. K2O + NH3(s)=
KNH2↓ + KOH (– 50 ºC).
KOH – KALIY GIDROKSID
KOH + HCl(suyul.) = KCl + H2O, KOH + HNO3(suyul.) = KNO3 + H2O.
2KOH + H2SO4(suyul.) = K 2SO 4 + 2H2O, KOH + H 2SO 4(kons., sovuq) = KHSO4 + H2O.
KOH(suyul.) + H3PO4(kons.) = KH2PO4 + H2O, 2KOH(suyul.) + H3PO4(suyul.) = K 2HPO 4 + 2H 2O,
3KOH(kons.) + H3PO4(suyul.) = K 3PO 4 + 3H2O.
KOH(suyul.) + HF(suyul.) = KF + H2O, KOH(kons.) + 2HF(kons.) = K(НF2) + H2O. KOH(kons.) + HCN = KCN + H2O.
2KOH(kons., sovuq) + E2 = KEO + KE + H2O (E = Cl, Br, I),
6KOH(kons., issiq) + 3E 2 = KEO3 + 5KE + 3H 2O.
3. 4KOH + 4O3 = 4KO3 + O2 + 2H2O (t ≤ 20 ºC).
2KOH(kons.) + 6H2O(issiq) + 2Al = 2K[Al(OH)4] + 3H2↑
2KOH(kons.) + EO2 = K2EO3 + H2O (E = C, S),
KOH + EO2 = KHEO 3↓ (etanolda).
6. 4KOH + 6NO = 4KNO2 + N2 + 2H2O (400 º).
2KOH(suyul.) + 2NO2 = KNO2 + KNO3 + H2O.
4KOH(issiq) + 4NO2 + O2 = 4KNO3 + 2H2O.
9. 2KOH + Al2O3 = 2KAlO 2 + H 2O (900 – 1100 º),
KOH + Al(OH) 3 = KAlO 2 + 2H 2O (1000 ºC).
2KOH(kons., issiq) + 3H2O + Al2O3 = 2K[Al(OH)4], KOH(kons.) + Al(OH)3 = K[Al(OH)4].
KOH(kons.) + NH4Cl(kons.) = KCl + NH3↑ + H2O (qaynash.).
2KOH(suyul.) + 2AgNO 3 = Ag 2O↓ + H 2O + 2KNO 3.
3KOH(suyul.) + AlCl 3 = Al(OH)3↓ + 3KCl,
4KOH(kons.) + AlCl 3 = K[Al(OH)4] + 3KCl.
6KOH(kons.) + 2H 2S + 4SO 2 = 3K2SO3S + 5H2O.
4KOH(s) elektroliz4K (katod) + О2↑ (anod) + 2H2O.
Rb – RUBIDIY
2Rb + 2H2O = 2RbOH + H2↑.
2Rb + 2HCl(suyul.) = 2RbCl + H2↑.
8Rb + 6H2SO4(suyul., sovuq) = 4Rb2SO4 + SO2 + S↓ + H2O (H2S qo’shimchasi). 4. 21Rb + 26HNO3(suyul., sovuq) = 21RbNO3 + NO↑ + N2O↑ + N2↑ + 13H2O.
5. 2Rb + 2RbOH = 2Rb 2O + H2 (400 C).
6. 2Rb + H2 = 2RbH (300 – 350 C).
Rb + O2(havo) = RbO2 (yonish).
4Rb + O2 = 2Rb2O (sovuqda),
9. 4Rb + O2 + 2H 2O = 4RbOH (20 C).
10. 2Rb + E2 = 2RbE (20 C, E = F, Cl, Br, I).
11. 2Rb + S = Rb2S (100 – 130 C).
9
12. 2Rb + 2H2S(to’yingan) = 2RbHS↓ + H2↑ (benzolda).
13. 2Rb + 2NH3(g) = 2RbNH2 + H2 (40 – 60 C).
RbH – RUBIDIY GIDRID
1. 2RbH = 2Rb + H2 (t > 200 C).
RbH + H2O = RbOH + H2↑.
RbH + HCl(suyul.) = RbCl + H2↑.
4. 2RbH + O2 = 2RbOH (t > 200 C).
5. RbH + Cl2 = RbCl + HCl (400 C),
2RbH + 2S = Rb2S + H2S (300 – 350 C).
6. RbH + NH3(s)= RbNH2 + H2 (300 C).
Rb2O – RUBIDIY OKSID
1. 2Rb2O = Rb2O2 + 2Rb (400 – 550 C).
Rb2O + H2O = 2RbOH.
Rb2O + 2HCl(suyul.) = 2RbCl + H2O.
Rb2O + CO2(nam) = Rb2CO3; Rb2O + H2O + CO2 = 2RbHCO3 (20 C).
Rb2O + NH3(s)
RbNH2↓ + RbOH (– 50 C).
RbOH – RUBIDIY GIDROKSID
1. RbOH + HCl(suyul.) = RbCl + H 2O, 2RbOH + H2SO4(suyul.) = Rb 2SO 4 + H2O, RbOH + HNO 3(suyul.) = RbNO 3 + H2O.
2. 4RbOH(s)+ 3O2 = 4RbO2 + 2H2O (450 C),
4RbOH + 4O3 = 4RbO3 + O2 + 2H2O (20 C).
2RbOH(kons.) + CO2 = Rb2CO3 + H2O.
RbOH(s) elektroliz4Rb (katod) + O2↑ (anod) + 2H2O.
Cs – SEZIY
1.2Cs + 2H2O = 2CsOH + H2↑.
2. 2Cs + 2HCl(suyul.) = 2CsCl + H2↑.
8Cs + 6H2SO4(suyul., sovuq) = 4Cs2SO4 + SO2↑ + S↓ + 6H2O (H2S qo’shimchasi), 21Cs + 26HNO3(suyul., sovuq) = 21CsNO3 + NO↑ + N2O↑ + N2↑ + 13H2O.
3. 2Cs + 2CsOH = 2Cs2O + H2↑ (300 – 350 C).
4. 2Cs + H2 = 2CsH (300 – 350 C, p).
5. Cs + O2(havo) = CsO2 (yondirish).
4Cs + O2 = 2Cs2O (sovuqda),
Cs O2 Cs O ↓
O2, CsO ↓ (– 50 C, suyuq NH
da).
2 2 2 3
4Cs + O2 + 2H2O = 4CsOH.
2Cs + E2 = 2CsE (20 C, E = F, Cl, Br, I).
2Cs + S = Cs2S (100 – 130 C).
2Cs + 2H2S(to’yingan) = 2CsHS↓ + H2↑ (benzolda).
2Cs + 6NH3(g) = 2CsNH2 + H2 (30 – 45 C).
CsH – SEZIY GIDRID
1. 2CsH = 2Cs + H2 (t > 200 C).
CsH + H2O = CsOH + H2↑.
CsH + HCl(suyul.) = CsCl + H2↑.
4. 2CsH + O2 = 2CsOH (t > 200 C).
5. CsH + Cl2 = CsCl + HCl (400 C),
2CsH + 2S = Cs2S + H2S (300 – 350 C).
6. CsH + NH3(g) = СsNH2 + H2↑ (350 C).
Cs2O – SEZIY OKSID
1. 2Cs2O = Cs2O2 + 2Cs (300 – 500 C).
8
Do'stlaringiz bilan baham: |